X-ray crystal structures of hexa-oxotellurate complexes of ruthenium(VI) and silver(III): Na-6 [RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O and Na-5[Ag{TeO4(OH)(2)}(2)] ? 16H(2)O
X-ray crystal structures of hexa-oxotellurate complexes of ruthenium(VI) and silver(III): Na-6 [RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O and Na-5[Ag{TeO4(OH)(2)}(2)] ? 16H(2)O
X-ray crystal structures are reported for Na-6[RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O and Na-5[Ag{TeO4(OH)(2)}(2)] ? 16H(2)O which contain respectively Ru-VI and Ag-III coordinated to chelating bidentate tellurate ([TeO4(OH)(2)](4-)) groups. Na-6[RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O: Space group P(1) over bar, Z = 2. lattice dimensions at 120 K; a = 6.9865(1), b = 8.7196(2) c = 11.7395(2) Angstrom, alpha = 74.008(1), beta = 79.954(1), gamma = 88.514(1)degrees R1 = 0.025. Na-5[Ag{TeO4(OH)(2)}(2)] . 16H(2)O: Space group P(1) over bar. Z = 2, lattice dimensions at 120 K a = 5.888(1), b = 8.932(1), c = 12.561(2) Angstrom, alpha = 98.219(6), beta = 97.964(9), gamma = 93.238(14)degrees; R1 = 0.047.
tellurates, ruthenium, silver, crystal structure, coordination chemistry, periodate
815-818
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Hill, Nicholas J.
c588ad7e-5668-46b9-b84a-791b664f37aa
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
2002
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Hill, Nicholas J.
c588ad7e-5668-46b9-b84a-791b664f37aa
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Hector, Andrew L., Hill, Nicholas J., Levason, William and Webster, Michael
(2002)
X-ray crystal structures of hexa-oxotellurate complexes of ruthenium(VI) and silver(III): Na-6 [RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O and Na-5[Ag{TeO4(OH)(2)}(2)] ? 16H(2)O.
Zeitschrift für anorganische und allgemeine Chemie, 628 (4), .
(doi:10.1002/1521-3749(200205)628:4<815::AID-ZAAC815>3.0.CO;2-U).
Abstract
X-ray crystal structures are reported for Na-6[RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O and Na-5[Ag{TeO4(OH)(2)}(2)] ? 16H(2)O which contain respectively Ru-VI and Ag-III coordinated to chelating bidentate tellurate ([TeO4(OH)(2)](4-)) groups. Na-6[RuO2{TeO4(OH)(2)}(2)] ? 16H(2)O: Space group P(1) over bar, Z = 2. lattice dimensions at 120 K; a = 6.9865(1), b = 8.7196(2) c = 11.7395(2) Angstrom, alpha = 74.008(1), beta = 79.954(1), gamma = 88.514(1)degrees R1 = 0.025. Na-5[Ag{TeO4(OH)(2)}(2)] . 16H(2)O: Space group P(1) over bar. Z = 2, lattice dimensions at 120 K a = 5.888(1), b = 8.932(1), c = 12.561(2) Angstrom, alpha = 98.219(6), beta = 97.964(9), gamma = 93.238(14)degrees; R1 = 0.047.
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Published date: 2002
Keywords:
tellurates, ruthenium, silver, crystal structure, coordination chemistry, periodate
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Chemistry
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Local EPrints ID: 19768
URI: http://eprints.soton.ac.uk/id/eprint/19768
ISSN: 0044-2313
PURE UUID: 37f65b2b-84d3-41d9-8128-304da7711306
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Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 02:53
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Author:
Nicholas J. Hill
Author:
Michael Webster
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