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Poly hexaacetatodiethanoltrimagnesium(II) diethanol solvate , a polymeric acetate-bridged magnesium chain structure

Poly hexaacetatodiethanoltrimagnesium(II) diethanol solvate , a polymeric acetate-bridged magnesium chain structure
Poly hexaacetatodiethanoltrimagnesium(II) diethanol solvate , a polymeric acetate-bridged magnesium chain structure
The title compound, [Mg3(C2H3O2)6(C2H6O)2]·2C2H6O, contains infinite chains of magnesium ions bridged by acetate ligands in three different coordination modes. There are two independent MgII ions in the asymmetric unit, and one lies on a twofold axis. The coordination geometry around each Mg ion is distorted octahedral.
M628-M630
Hector, A. L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Mayer, T. A.
7745fac9-3d30-431e-a045-acfdf1ce7000
Hector, A. L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Mayer, T. A.
7745fac9-3d30-431e-a045-acfdf1ce7000

Hector, A. L. and Mayer, T. A. (2002) Poly hexaacetatodiethanoltrimagnesium(II) diethanol solvate , a polymeric acetate-bridged magnesium chain structure. Acta Crystallographica Section E Crystallographic Communications, 58 (11), M628-M630. (doi:10.1107/S1600536802018378).

Record type: Article

Abstract

The title compound, [Mg3(C2H3O2)6(C2H6O)2]·2C2H6O, contains infinite chains of magnesium ions bridged by acetate ligands in three different coordination modes. There are two independent MgII ions in the asymmetric unit, and one lies on a twofold axis. The coordination geometry around each Mg ion is distorted octahedral.

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Published date: 1 November 2002

Identifiers

Local EPrints ID: 19769
URI: http://eprints.soton.ac.uk/id/eprint/19769
PURE UUID: 5bc5955e-35cc-4dd3-bb0e-fecfdcac1644
ORCID for A. L. Hector: ORCID iD orcid.org/0000-0002-9964-2163

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Date deposited: 16 Feb 2006
Last modified: 12 Dec 2021 02:56

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Contributors

Author: A. L. Hector ORCID iD
Author: T. A. Mayer

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