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Synthesis and complexation of a new facultative tridentate S2Te donor ligand MeS(CH2)3Te(CH2)3SMe: crystal structures of [Rh(Cp*)(S2Te)][PF6]2 and [PtCl(S2Te)]PF6

Synthesis and complexation of a new facultative tridentate S2Te donor ligand MeS(CH2)3Te(CH2)3SMe: crystal structures of [Rh(Cp*)(S2Te)][PF6]2 and [PtCl(S2Te)]PF6
Synthesis and complexation of a new facultative tridentate S2Te donor ligand MeS(CH2)3Te(CH2)3SMe: crystal structures of [Rh(Cp*)(S2Te)][PF6]2 and [PtCl(S2Te)]PF6
The syntheses and spectroscopic characterisation of the new facultative tridentate tellurium containing ligands MeS(CH2)3Te(CH2)3SMe (S2Te) and H2N(CH2)3Te(CH2)3NH2 are described. The complexes of the former, fac-[Mn(CO)3(S2Te)]CF3SO3, [Rh(Cp*)(S2Te)][PF6]2, [MCl(S2Te)]PF6 (M=Pd or Pt), [Cu(S2Te)]BF4 and [Ag(S2Te)]CF3SO3 have been prepared and characterised by analysis, IR, 1H-, 13C{1H}-, 125Te- and 195Pt-NMR spectroscopy and mass spectrometry. The X-ray crystal structures of [Rh(Cp*)(S2Te)][PF6]2 and [PtCl(S2Te)]PF6 are described. The results are compared with those obtained from complexes of the related tridentates Te{(CH2)3TeR}2, Se{(CH2)3SeMe}2 and S{(CH2)3SR}2.
telluroether, thioether, rhoditum, platinum, copper, nuclear-magnetic-resonance, metal-complexes, selenium, selenoether, sulfur, ph
0022-328X
214-218
Hesford, Matthew
fdd3d10d-5d9e-4149-b614-12dcd0d52f1a
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Orchard, Simon D.
1bc4b4f8-fd4e-4289-a07c-f79dbbfc5d66
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Hesford, Matthew
fdd3d10d-5d9e-4149-b614-12dcd0d52f1a
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Orchard, Simon D.
1bc4b4f8-fd4e-4289-a07c-f79dbbfc5d66
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Hesford, Matthew, Levason, William, Orchard, Simon D. and Reid, Gillian (2002) Synthesis and complexation of a new facultative tridentate S2Te donor ligand MeS(CH2)3Te(CH2)3SMe: crystal structures of [Rh(Cp*)(S2Te)][PF6]2 and [PtCl(S2Te)]PF6. Journal of Organometallic Chemistry, 649 (2), 214-218. (doi:10.1016/S0022-328X(02)01130-0).

Record type: Article

Abstract

The syntheses and spectroscopic characterisation of the new facultative tridentate tellurium containing ligands MeS(CH2)3Te(CH2)3SMe (S2Te) and H2N(CH2)3Te(CH2)3NH2 are described. The complexes of the former, fac-[Mn(CO)3(S2Te)]CF3SO3, [Rh(Cp*)(S2Te)][PF6]2, [MCl(S2Te)]PF6 (M=Pd or Pt), [Cu(S2Te)]BF4 and [Ag(S2Te)]CF3SO3 have been prepared and characterised by analysis, IR, 1H-, 13C{1H}-, 125Te- and 195Pt-NMR spectroscopy and mass spectrometry. The X-ray crystal structures of [Rh(Cp*)(S2Te)][PF6]2 and [PtCl(S2Te)]PF6 are described. The results are compared with those obtained from complexes of the related tridentates Te{(CH2)3TeR}2, Se{(CH2)3SeMe}2 and S{(CH2)3SR}2.

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Published date: 22 April 2002
Keywords: telluroether, thioether, rhoditum, platinum, copper, nuclear-magnetic-resonance, metal-complexes, selenium, selenoether, sulfur, ph

Identifiers

Local EPrints ID: 19771
URI: http://eprints.soton.ac.uk/id/eprint/19771
ISSN: 0022-328X
PURE UUID: 4e445f82-53f5-49f9-a806-01d7ee0d23fa
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 20 Feb 2006
Last modified: 09 Jan 2022 02:43

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Contributors

Author: Matthew Hesford
Author: William Levason ORCID iD
Author: Simon D. Orchard
Author: Gillian Reid ORCID iD

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