The University of Southampton
University of Southampton Institutional Repository

Structure of bis(2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazonato) palladium(II), a potential antitumor complex

Structure of bis(2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazonato) palladium(II), a potential antitumor complex
Structure of bis(2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazonato) palladium(II), a potential antitumor complex
The crystal structure of the potential antitumor complex bis(2-acetyppyridine 3-hexamethyleneiminylthiosemicarbazonato)palladium(II) has been solved. The palladium(H) atom is in a square planar environment surrounded by two cis nitrogen atoms and two cis sulfur atoms. The ligands are not equivalent, one being tridentate with (N,N,S) donation, the other being monodentate using only the sulfur atom to coordinate to the metal. The tridentate ligand shows a Z, E, Z configuration while the monodentate ligand shows an E, E, Z. Intermolecular hydrogen bonds stabilize the structure, while the crystal packing is determined by Pd-C, Pd-?, C-H-? and ?-? interactions.
palladium(ii) complexes, thiosemicarbazonato complexes, crystal structure, antitumor activity, spectral properties, 2-acetylpyridine, thiosemicarbazone, derivatives
0162-0134
137-140
Kovala-Demertzi, Dimitra
f1f7122a-ea60-4b34-a882-a3ef4416282e
Demertzis, Mavroudis A.
2096f486-765f-4916-982d-b8676ee72b10
Miller, John R.
51ae0abf-cda3-459e-bc0d-e449e8371589
Frampton, Christopher S.
91f7b381-6040-4c82-94d7-4edf37c71549
Jasinski, Jerry P.
7d01281e-3b67-41ca-a875-f360189a9edb
West, Douglas X.
91ef63ae-0eb0-46fd-ab05-2a0ab9233d27
Kovala-Demertzi, Dimitra
f1f7122a-ea60-4b34-a882-a3ef4416282e
Demertzis, Mavroudis A.
2096f486-765f-4916-982d-b8676ee72b10
Miller, John R.
51ae0abf-cda3-459e-bc0d-e449e8371589
Frampton, Christopher S.
91f7b381-6040-4c82-94d7-4edf37c71549
Jasinski, Jerry P.
7d01281e-3b67-41ca-a875-f360189a9edb
West, Douglas X.
91ef63ae-0eb0-46fd-ab05-2a0ab9233d27

Kovala-Demertzi, Dimitra, Demertzis, Mavroudis A., Miller, John R., Frampton, Christopher S., Jasinski, Jerry P. and West, Douglas X. (2002) Structure of bis(2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazonato) palladium(II), a potential antitumor complex. Journal of Inorganic Biochemistry, 92 (2), 137-140. (doi:10.1016/S0162-0134(02)00493-2).

Record type: Article

Abstract

The crystal structure of the potential antitumor complex bis(2-acetyppyridine 3-hexamethyleneiminylthiosemicarbazonato)palladium(II) has been solved. The palladium(H) atom is in a square planar environment surrounded by two cis nitrogen atoms and two cis sulfur atoms. The ligands are not equivalent, one being tridentate with (N,N,S) donation, the other being monodentate using only the sulfur atom to coordinate to the metal. The tridentate ligand shows a Z, E, Z configuration while the monodentate ligand shows an E, E, Z. Intermolecular hydrogen bonds stabilize the structure, while the crystal packing is determined by Pd-C, Pd-?, C-H-? and ?-? interactions.

This record has no associated files available for download.

More information

Published date: 11 November 2002
Keywords: palladium(ii) complexes, thiosemicarbazonato complexes, crystal structure, antitumor activity, spectral properties, 2-acetylpyridine, thiosemicarbazone, derivatives

Identifiers

Local EPrints ID: 19789
URI: http://eprints.soton.ac.uk/id/eprint/19789
ISSN: 0162-0134
PURE UUID: ff0fedac-fc4a-46ec-8569-74afcaf21bb9

Catalogue record

Date deposited: 21 Feb 2006
Last modified: 22 Jul 2022 20:27

Export record

Altmetrics

Contributors

Author: Dimitra Kovala-Demertzi
Author: Mavroudis A. Demertzis
Author: John R. Miller
Author: Christopher S. Frampton
Author: Jerry P. Jasinski
Author: Douglas X. West

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×