Ethyl 3-(diphenylphosphinoyl)-3-phenylpropionate

Light, M. E., Murphy, P. J., Hancock, P. and Hursthouse, M. B. (2002) Ethyl 3-(diphenylphosphinoyl)-3-phenylpropionate Acta Crystallographica Section E Crystallographic Communications, 58, (9), o990-o991. (doi:10.1107/S1600536802014642).


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The title compound, Ph2P(O)CH(Ph)CH2COOEt or C23H23O3P, (I), assembles into columns extending down the a axis, via C-H...O hydrogen bonds. Compound (I) was isolated as a by-product in studies related to the development of a novel cyclization reaction [Evans et al. (2002). Tetrahedron Lett. 43, 299-301] and was synthesized independently to confirm its structure.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1107/S1600536802014642
Related URLs:
ePrint ID: 19807
Date :
Date Event
1 September 2002Published
Date Deposited: 16 Feb 2006
Last Modified: 16 Apr 2017 23:00
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