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Ethyl 3-(diphenylphosphinoyl)-3-phenylpropionate

Ethyl 3-(diphenylphosphinoyl)-3-phenylpropionate
Ethyl 3-(diphenylphosphinoyl)-3-phenylpropionate
The title compound, Ph2P(O)CH(Ph)CH2COOEt or C23H23O3P, (I), assembles into columns extending down the a axis, via C-H...O hydrogen bonds. Compound (I) was isolated as a by-product in studies related to the development of a novel cyclization reaction [Evans et al. (2002). Tetrahedron Lett. 43, 299-301] and was synthesized independently to confirm its structure.
o990-o991
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Murphy, P. J.
e361583b-6b55-4418-a536-24f3405273a2
Hancock, P.
ddf17cfe-84c6-493d-a525-638f227be9fc
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Murphy, P. J.
e361583b-6b55-4418-a536-24f3405273a2
Hancock, P.
ddf17cfe-84c6-493d-a525-638f227be9fc
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Light, M. E., Murphy, P. J., Hancock, P. and Hursthouse, M. B. (2002) Ethyl 3-(diphenylphosphinoyl)-3-phenylpropionate. Acta Crystallographica Section E Crystallographic Communications, 58 (9), o990-o991. (doi:10.1107/S1600536802014642).

Record type: Article

Abstract

The title compound, Ph2P(O)CH(Ph)CH2COOEt or C23H23O3P, (I), assembles into columns extending down the a axis, via C-H...O hydrogen bonds. Compound (I) was isolated as a by-product in studies related to the development of a novel cyclization reaction [Evans et al. (2002). Tetrahedron Lett. 43, 299-301] and was synthesized independently to confirm its structure.

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Published date: 1 September 2002

Identifiers

Local EPrints ID: 19807
URI: http://eprints.soton.ac.uk/id/eprint/19807
PURE UUID: ebbc6b80-0f13-4e99-ac78-6c326749c75a
ORCID for M. E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 16 Feb 2006
Last modified: 12 Dec 2021 03:05

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Contributors

Author: M. E. Light ORCID iD
Author: P. J. Murphy
Author: P. Hancock

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