Recoverable catalysts and reagents using recyclable polystyrene-based supports

McNamara, Catherine A., Dixon, Mark J. and Bradley, Mark (2002) Recoverable catalysts and reagents using recyclable polystyrene-based supports. Chemical Reviews, 102 (10), 3275-3300. (doi:10.1021/cr0103571).

Abstract

Contents
1.0Introduction 1.1 Polystyrene Supports as Carriers for Reagents and Catalysts 1.2 Catalyst and Reagent Attachment to Polymer Supports 2.0C-C Bond Formation Using Recyclable Resin-Based Reagents and Catalysts 2.1 Palladium-Catalyzed Coupling Reactions 2.2 Other Transition Metal Catalyzed Reactions 2.3 Resin-Supported Olefin Metathesis 2.4 Resin-Mediated Cycloaddition Reactions 2.4.1 Diels-Alder Cycloadditions 2.4.2 Resin-Based Catalysts for 1,3-Dipolar Cycloadditions 2.5 Immobilized Chiral Ligands for Diethylzinc Additions to Aldehydes 2.6 Miscellaneous: Other C-C Bond Forming Reactions 3.0Immobilized Oxidants 3.1Oxidation with Immobilized Transition Metal Complexes 3.2 Alcohol Oxidation 3.3 Alkene Oxidation 3.3.1 Dihydroxylation 3.3.2 Epoxidation 3.3.3 Asymmetric Epoxidation 3.3.4 Other Alkene Oxidation Reactions 3.4 Potpourri: Other Immobilized Oxidants 4.0Immobilized Resin-Based Reductants 4.1 General Reduction Processes 4.2 Asymmetric Reduction of Ketones 4.3 Alkene Reduction 4.4 Resin-Based Tin and Germanium Reductants 5.0Conclusions 6.0Abbreviations 7.0Acknowledgments 8.0References

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