The dipole polarizability of the hydrogen molecular cation HD+ and other isotopomers
The dipole polarizability of the hydrogen molecular cation HD+ and other isotopomers
Fully non-adiabatic calculations are reported of the electric dipole polarizabilities for the N = 0 and N = 1 levels of the ground electronic states of H-2(+) (v less than or equal to 16), D-2(+) (v less than or equal to 24) and HD+ (v less than or equal to 20). For H-2(+) (v = 0, N = 0) the calculated value still differs from the experimental value; this difference cannot be explained by the inclusion of higher order contributions.
transformed hamiltonian theory, vibration-rotation levels, d-2(+)
ground-states, microwave spectroscopy, rydberg states, h-2(+), ion, values
1527-1535
Moss, R.E.
5d410492-850a-4950-85fd-2deb89f60859
Valenzano, L.
5dc37261-a2d5-4d56-b7fc-059c1c4e7738
20 May 2002
Moss, R.E.
5d410492-850a-4950-85fd-2deb89f60859
Valenzano, L.
5dc37261-a2d5-4d56-b7fc-059c1c4e7738
Moss, R.E. and Valenzano, L.
(2002)
The dipole polarizability of the hydrogen molecular cation HD+ and other isotopomers.
Molecular Physics, 100 (10), .
Abstract
Fully non-adiabatic calculations are reported of the electric dipole polarizabilities for the N = 0 and N = 1 levels of the ground electronic states of H-2(+) (v less than or equal to 16), D-2(+) (v less than or equal to 24) and HD+ (v less than or equal to 20). For H-2(+) (v = 0, N = 0) the calculated value still differs from the experimental value; this difference cannot be explained by the inclusion of higher order contributions.
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Published date: 20 May 2002
Keywords:
transformed hamiltonian theory, vibration-rotation levels, d-2(+)
ground-states, microwave spectroscopy, rydberg states, h-2(+), ion, values
Identifiers
Local EPrints ID: 19822
URI: http://eprints.soton.ac.uk/id/eprint/19822
ISSN: 0026-8976
PURE UUID: 7038de94-9a99-4aa6-8e3c-bb24e22c8d67
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Date deposited: 21 Feb 2006
Last modified: 08 Jan 2022 12:50
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Contributors
Author:
R.E. Moss
Author:
L. Valenzano
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