Mesoporous nickel/nickel oxide-a nanoarchitectured electrode

Nelson, Phillip A., Elliott, Joanne M., Attard, George S. and Owen, John R. (2002) Mesoporous nickel/nickel oxide-a nanoarchitectured electrode Chemistry of Materials, 14, (2), pp. 524-529. (doi:10.1021/cm011021a).


Full text not available from this repository.


Metallic nickel was electrodeposited from aqueous nickel(II) acetate dissolved in the lyotropic liquid crystalline phases of Brij 56 and Brij 78 surfactant templates to form metal films with hexagonal arrays of nanometer-sized channels. The applicability of these materials as inexpensive, large area and low-resistance current collectors was demonstrated by cyclic voltammetry. The redox charge capacity of the surface oxide in aqueous KOH was enhanced by 2 orders of magnitude over that of a nontemplated sample with no detectable impedance of the reaction rate.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1021/cm011021a
ISSNs: 0897-4756 (print)
Keywords: liquid-crystalline phases, molecular-sieves, nickel, films, oxidation, behavior
ePrint ID: 19827
Date :
Date Event
Date Deposited: 21 Feb 2006
Last Modified: 16 Apr 2017 23:00
Further Information:Google Scholar

Actions (login required)

View Item View Item