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A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6

A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6
A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6
The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)(2)SbNa(THF)(2)](6) 1 has been synthesised and structurally characterised from the reaction between 3-Me-1,2-C6H3(OH)(ONa) and (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2).
metallacycle
1359-7345
2150-2151
Paver, M.A.
1d01a98a-0b92-482a-8ee6-8909f57a2187
Joy, J.S.
e3443670-4059-4810-ba8a-de7d65d572f8
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Paver, M.A.
1d01a98a-0b92-482a-8ee6-8909f57a2187
Joy, J.S.
e3443670-4059-4810-ba8a-de7d65d572f8
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Paver, M.A., Joy, J.S. and Hursthouse, M.B. (2002) A twenty-four membered mixed-metal macrocycle; synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6. Chemical Communications, n/a (18), 2150-2151. (doi:10.1039/b206228c).

Record type: Article

Abstract

The first example of a twenty-four membered mixed p-/s-block macrocycle, cyclo-[(3-Me-1,2-C6H3O2)(2)SbNa(THF)(2)](6) 1 has been synthesised and structurally characterised from the reaction between 3-Me-1,2-C6H3(OH)(ONa) and (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2).

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Published date: 2002
Keywords: metallacycle

Identifiers

Local EPrints ID: 19834
URI: http://eprints.soton.ac.uk/id/eprint/19834
ISSN: 1359-7345
PURE UUID: 4f1586e0-0c68-4a07-8fc9-7aebcf58de7b

Catalogue record

Date deposited: 22 Feb 2006
Last modified: 08 Jan 2022 06:46

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Contributors

Author: M.A. Paver
Author: J.S. Joy
Author: M.B. Hursthouse

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