Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes
Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes
Samarium diiodide mediated cyclisation of methylenecyclopropyl ketones, readily prepared from beta-ketoesters provides a simple route to bicyclo-[3.2.1]-octanes.
methylenecyclopropane, samarium diiodide, cyclisation
samarium(ii) iodide, cyclizations, derivatives
6201-6203
Saint-Dizier, A. C.
e7ac8879-2454-4149-93b1-326521337f27
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
26 August 2002
Saint-Dizier, A. C.
e7ac8879-2454-4149-93b1-326521337f27
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
Saint-Dizier, A. C. and Kilburn, J. D.
(2002)
Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes.
Tetrahedron Letters, 43 (35), .
(doi:10.1016/S0040-4039(02)01329-1).
Abstract
Samarium diiodide mediated cyclisation of methylenecyclopropyl ketones, readily prepared from beta-ketoesters provides a simple route to bicyclo-[3.2.1]-octanes.
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Published date: 26 August 2002
Keywords:
methylenecyclopropane, samarium diiodide, cyclisation
samarium(ii) iodide, cyclizations, derivatives
Identifiers
Local EPrints ID: 19847
URI: http://eprints.soton.ac.uk/id/eprint/19847
ISSN: 0040-4039
PURE UUID: 2de3ec23-9ed2-4663-960c-012fa97d98c1
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Date deposited: 17 Feb 2006
Last modified: 15 Mar 2024 06:19
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Author:
A. C. Saint-Dizier
Author:
J. D. Kilburn
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