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Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes

Record type: Article

Samarium diiodide mediated cyclisation of methylenecyclopropyl ketones, readily prepared from beta-ketoesters provides a simple route to bicyclo-[3.2.1]-octanes.

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Citation

Saint-Dizier, A. C. and Kilburn, J. D. (2002) Cascade radical cyclisations of methylenecyclopropyl ketones - synthesis of bicyclo- 3.2.1 -octanes Tetrahedron Letters, 43, (35), pp. 6201-6203. (doi:10.1016/S0040-4039(02)01329-1).

More information

Published date: 26 August 2002
Keywords: methylenecyclopropane, samarium diiodide, cyclisation samarium(ii) iodide, cyclizations, derivatives

Identifiers

Local EPrints ID: 19847
URI: http://eprints.soton.ac.uk/id/eprint/19847
ISSN: 0040-4039
PURE UUID: 2de3ec23-9ed2-4663-960c-012fa97d98c1

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Date deposited: 17 Feb 2006
Last modified: 17 Jul 2017 16:30

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Contributors

Author: A. C. Saint-Dizier
Author: J. D. Kilburn

University divisions


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