Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH]
Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH]
The title compound [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH] was obtained during the reaction of Me2SnCl2 with the sodium salt of the ligand in 1:2 molar ratio in a refluxing methanol–benzene mixture. X-ray diffraction analysis of the compound reveals that it is the first tetraorganodistannoxane structural motif in which two molecules of free oxime are connected to the stannoxane framework and the two Sn---O distances of the four-membered planar Sn2O2 ring are identical.
tetraorganodistannoxanes, internally functionalized oxime, crystal
structures, nmr
66-69
Sharma, Vinita
7389c0c1-69ca-42ea-875a-a29cafcf8cda
Sharma, Rajnish K.
ca082c38-d6dc-4913-9c4a-a02c8c2f7c7b
Bohra, Rakesh
992e54e6-6f5d-47f1-8ddc-121dc0d1f796
Jain, Vimal K.
015a82e5-71eb-4107-8f06-7bffeb602553
Drake, John E.
6de1350f-4eb6-4ca7-b796-947f4fec467d
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
16 December 2002
Sharma, Vinita
7389c0c1-69ca-42ea-875a-a29cafcf8cda
Sharma, Rajnish K.
ca082c38-d6dc-4913-9c4a-a02c8c2f7c7b
Bohra, Rakesh
992e54e6-6f5d-47f1-8ddc-121dc0d1f796
Jain, Vimal K.
015a82e5-71eb-4107-8f06-7bffeb602553
Drake, John E.
6de1350f-4eb6-4ca7-b796-947f4fec467d
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Sharma, Vinita, Sharma, Rajnish K., Bohra, Rakesh, Jain, Vimal K., Drake, John E., Light, Mark E. and Hursthouse, Michael B.
(2002)
Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH].
Journal of Organometallic Chemistry, 664 (1-2), .
(doi:10.1016/S0022-328X(02)01904-6).
Abstract
The title compound [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH] was obtained during the reaction of Me2SnCl2 with the sodium salt of the ligand in 1:2 molar ratio in a refluxing methanol–benzene mixture. X-ray diffraction analysis of the compound reveals that it is the first tetraorganodistannoxane structural motif in which two molecules of free oxime are connected to the stannoxane framework and the two Sn---O distances of the four-membered planar Sn2O2 ring are identical.
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Published date: 16 December 2002
Keywords:
tetraorganodistannoxanes, internally functionalized oxime, crystal
structures, nmr
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Local EPrints ID: 19851
URI: http://eprints.soton.ac.uk/id/eprint/19851
ISSN: 0022-328X
PURE UUID: 6eed9a74-2ae8-4230-b67a-99f165661b3e
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Date deposited: 22 Feb 2006
Last modified: 16 Mar 2024 03:04
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Contributors
Author:
Vinita Sharma
Author:
Rajnish K. Sharma
Author:
Rakesh Bohra
Author:
Vimal K. Jain
Author:
John E. Drake
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