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Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH]

Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH]
Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH]
The title compound [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH] was obtained during the reaction of Me2SnCl2 with the sodium salt of the ligand in 1:2 molar ratio in a refluxing methanol–benzene mixture. X-ray diffraction analysis of the compound reveals that it is the first tetraorganodistannoxane structural motif in which two molecules of free oxime are connected to the stannoxane framework and the two Sn---O distances of the four-membered planar Sn2O2 ring are identical.
tetraorganodistannoxanes, internally functionalized oxime, crystal structures, nmr
0022-328X
66-69
Sharma, Vinita
7389c0c1-69ca-42ea-875a-a29cafcf8cda
Sharma, Rajnish K.
ca082c38-d6dc-4913-9c4a-a02c8c2f7c7b
Bohra, Rakesh
992e54e6-6f5d-47f1-8ddc-121dc0d1f796
Jain, Vimal K.
015a82e5-71eb-4107-8f06-7bffeb602553
Drake, John E.
6de1350f-4eb6-4ca7-b796-947f4fec467d
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Sharma, Vinita
7389c0c1-69ca-42ea-875a-a29cafcf8cda
Sharma, Rajnish K.
ca082c38-d6dc-4913-9c4a-a02c8c2f7c7b
Bohra, Rakesh
992e54e6-6f5d-47f1-8ddc-121dc0d1f796
Jain, Vimal K.
015a82e5-71eb-4107-8f06-7bffeb602553
Drake, John E.
6de1350f-4eb6-4ca7-b796-947f4fec467d
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Sharma, Vinita, Sharma, Rajnish K., Bohra, Rakesh, Jain, Vimal K., Drake, John E., Light, Mark E. and Hursthouse, Michael B. (2002) Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH]. Journal of Organometallic Chemistry, 664 (1-2), 66-69. (doi:10.1016/S0022-328X(02)01904-6).

Record type: Article

Abstract

The title compound [{Me2Sn(ON=C(Me)C5H4N)}2O}]2·2[2-NC5H4(Me)C=NOH] was obtained during the reaction of Me2SnCl2 with the sodium salt of the ligand in 1:2 molar ratio in a refluxing methanol–benzene mixture. X-ray diffraction analysis of the compound reveals that it is the first tetraorganodistannoxane structural motif in which two molecules of free oxime are connected to the stannoxane framework and the two Sn---O distances of the four-membered planar Sn2O2 ring are identical.

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More information

Published date: 16 December 2002
Keywords: tetraorganodistannoxanes, internally functionalized oxime, crystal structures, nmr

Identifiers

Local EPrints ID: 19851
URI: http://eprints.soton.ac.uk/id/eprint/19851
ISSN: 0022-328X
PURE UUID: 6eed9a74-2ae8-4230-b67a-99f165661b3e
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 22 Feb 2006
Last modified: 09 Jan 2022 02:59

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Contributors

Author: Vinita Sharma
Author: Rajnish K. Sharma
Author: Rakesh Bohra
Author: Vimal K. Jain
Author: John E. Drake
Author: Mark E. Light ORCID iD

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