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N- 2-(4-methoxyphenyltelluro)ethyl benzamide (L-1) and N- 2-(4-methoxyphenyl telluro)propyl phthalimide (L-2): synthesis and ligation with palladium(II), platinum(II) and ruthenium(II). Crystal structures of L-1 and L-2, the latter as a mixed crystal with (LH2)-H-2

N- 2-(4-methoxyphenyltelluro)ethyl benzamide (L-1) and N- 2-(4-methoxyphenyl telluro)propyl phthalimide (L-2): synthesis and ligation with palladium(II), platinum(II) and ruthenium(II). Crystal structures of L-1 and L-2, the latter as a mixed crystal with (LH2)-H-2
N- 2-(4-methoxyphenyltelluro)ethyl benzamide (L-1) and N- 2-(4-methoxyphenyl telluro)propyl phthalimide (L-2): synthesis and ligation with palladium(II), platinum(II) and ruthenium(II). Crystal structures of L-1 and L-2, the latter as a mixed crystal with (LH2)-H-2
yThe reactions of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te2, have resulted in N-[2-(4-methoxyphenyltelluro)ethyl]benzamide (L-1) and N-[2-(4-methoxyphenyltelluro)propyl] phthalimide (L-2) respectively. The L-1 and L-2 both exhibit characteristic H-1 and C-13 NMR spectra. The single crystal structures of L-1 and L-2, the latter as a mixed crystal with (LH2)-H-2 are determined by X-ray diffraction (XRD). The Te-C(alkyl) bond length is 2.140(8)/2.149(4) Angstrom and longer than Te-C(aryl), 2.107(8)/2.123(5) Angstrom. The complexes having stoichiometries [PdCl2(L-1)] (1), [PtCl2(L-1)](2), [(Phen)Pd(L-1)](ClO4)(2) (3), [(DPPE)Pd(L-1)](ClO4), (4) and [RuCl2(L-2)(2)] (5) were synthesized and characterized by elemental analyses, conductance and molecular weight measurements, NMR (H-1 and C-13) and FT-IR spectra. The deshielding of CH2Te ( similar to 0.2 ppm in H-1 NMR and up to 22 ppm in C-13{H-1} NMR) and NH signals (upto 0.8 ppm in H-1 NMR) of 1 -4, with respect to those of free L-1 indicates that L-1 coordinates with Pd-Pt(II) as a (Te, N) ligand. The CH2Te/CH2N signals in H-1 and C-13 NNIR spectra of 5 appear deshielded (0.8/0.14 and 20/8 ppm, respectively), when compared with those of free L2, indicating ligation of L-2 via Te and N.
n-[2-(4-methoxyphenyltelluro)ethyl]benzamide, n-[2-(4-methoxyphenyl telluro)propyl]phthalimide, palladium(ii), platinum(ii), ruthenium(ii), complexes, crystal structureshybrid organotellurium ligands, ditelluroether complexes, mercury(ii), diorganotellurides, chemistry, tellurium, chloride, te
0277-5387
667-674
Singh, A. K.
c8db0073-98b0-436c-8247-1cdda740765c
Sooriyakumar, J.
f150a0af-bd9f-4214-a7e6-642dd582729b
Kadarkaraisamy, M.
4736f5c7-a996-45f3-871c-51dbb977d1d3
Drake, J. E.
dee0cd4d-79bf-4024-ad9c-d61bfaf9216b
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Butcher, R. J.
19b6c6d8-eada-423f-969f-310959612e58
Singh, A. K.
c8db0073-98b0-436c-8247-1cdda740765c
Sooriyakumar, J.
f150a0af-bd9f-4214-a7e6-642dd582729b
Kadarkaraisamy, M.
4736f5c7-a996-45f3-871c-51dbb977d1d3
Drake, J. E.
dee0cd4d-79bf-4024-ad9c-d61bfaf9216b
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Butcher, R. J.
19b6c6d8-eada-423f-969f-310959612e58

Singh, A. K., Sooriyakumar, J., Kadarkaraisamy, M., Drake, J. E., Hursthouse, M. B., Light, M. E. and Butcher, R. J. (2002) N- 2-(4-methoxyphenyltelluro)ethyl benzamide (L-1) and N- 2-(4-methoxyphenyl telluro)propyl phthalimide (L-2): synthesis and ligation with palladium(II), platinum(II) and ruthenium(II). Crystal structures of L-1 and L-2, the latter as a mixed crystal with (LH2)-H-2. Polyhedron, 21 (5-6), 667-674. (doi:10.1016/S0277-5387(02)00831-8).

Record type: Article

Abstract

yThe reactions of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te2, have resulted in N-[2-(4-methoxyphenyltelluro)ethyl]benzamide (L-1) and N-[2-(4-methoxyphenyltelluro)propyl] phthalimide (L-2) respectively. The L-1 and L-2 both exhibit characteristic H-1 and C-13 NMR spectra. The single crystal structures of L-1 and L-2, the latter as a mixed crystal with (LH2)-H-2 are determined by X-ray diffraction (XRD). The Te-C(alkyl) bond length is 2.140(8)/2.149(4) Angstrom and longer than Te-C(aryl), 2.107(8)/2.123(5) Angstrom. The complexes having stoichiometries [PdCl2(L-1)] (1), [PtCl2(L-1)](2), [(Phen)Pd(L-1)](ClO4)(2) (3), [(DPPE)Pd(L-1)](ClO4), (4) and [RuCl2(L-2)(2)] (5) were synthesized and characterized by elemental analyses, conductance and molecular weight measurements, NMR (H-1 and C-13) and FT-IR spectra. The deshielding of CH2Te ( similar to 0.2 ppm in H-1 NMR and up to 22 ppm in C-13{H-1} NMR) and NH signals (upto 0.8 ppm in H-1 NMR) of 1 -4, with respect to those of free L-1 indicates that L-1 coordinates with Pd-Pt(II) as a (Te, N) ligand. The CH2Te/CH2N signals in H-1 and C-13 NNIR spectra of 5 appear deshielded (0.8/0.14 and 20/8 ppm, respectively), when compared with those of free L2, indicating ligation of L-2 via Te and N.

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More information

Published date: 15 March 2002
Keywords: n-[2-(4-methoxyphenyltelluro)ethyl]benzamide, n-[2-(4-methoxyphenyl telluro)propyl]phthalimide, palladium(ii), platinum(ii), ruthenium(ii), complexes, crystal structureshybrid organotellurium ligands, ditelluroether complexes, mercury(ii), diorganotellurides, chemistry, tellurium, chloride, te

Identifiers

Local EPrints ID: 19855
URI: http://eprints.soton.ac.uk/id/eprint/19855
ISSN: 0277-5387
PURE UUID: d98a9704-2164-41dd-9549-0183d46ad396
ORCID for M. E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 16 Feb 2006
Last modified: 09 Jan 2022 02:59

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Contributors

Author: A. K. Singh
Author: J. Sooriyakumar
Author: M. Kadarkaraisamy
Author: J. E. Drake
Author: M. E. Light ORCID iD
Author: R. J. Butcher

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