Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study
Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study
Synchrotron far-IR light has allowed the rapid collection of high quality reflection-absorption infrared spectra of the metal-adsorbate stretching vibrations of CO adsorbed in atop (464 cm(-1)) and bridging (3 76 cm(-1)) sites on Pt{1 1 1} at half monolayer coverage at 260 K. In contrast to earlier reports we find no evidence for a Fermi resonance induced splitting of the absorption band assigned to the bridge bonded species.
infrared absorption spectroscopy, vibrations of adsorbed molecules, carbon monoxide, platinum, vibrational phase relaxation, dipole-forbidden modes, reflection-absorption, system pt(111)-co, spectroscopy, stretch, surfaces
L303-L306
Surman, Mark
fbb90d91-1a9e-473e-a603-5fdd53459375
Hagans, Patrick L.
ddee1ce7-3f80-43f4-9900-ba6de7c6fbbe
Wilson, Natalie E.
15d9ac4a-5da3-4f41-ac2b-196b06607746
Baily, Christopher J.
9ca8e7be-d044-47ea-955a-7ab8ce4754fe
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
2002
Surman, Mark
fbb90d91-1a9e-473e-a603-5fdd53459375
Hagans, Patrick L.
ddee1ce7-3f80-43f4-9900-ba6de7c6fbbe
Wilson, Natalie E.
15d9ac4a-5da3-4f41-ac2b-196b06607746
Baily, Christopher J.
9ca8e7be-d044-47ea-955a-7ab8ce4754fe
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
Surman, Mark, Hagans, Patrick L., Wilson, Natalie E., Baily, Christopher J. and Russell, Andrea E.
(2002)
Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study.
Surface Science, 511 (1-3), .
(doi:10.1016/S0039-6028(02)01565-0).
Abstract
Synchrotron far-IR light has allowed the rapid collection of high quality reflection-absorption infrared spectra of the metal-adsorbate stretching vibrations of CO adsorbed in atop (464 cm(-1)) and bridging (3 76 cm(-1)) sites on Pt{1 1 1} at half monolayer coverage at 260 K. In contrast to earlier reports we find no evidence for a Fermi resonance induced splitting of the absorption band assigned to the bridge bonded species.
This record has no associated files available for download.
More information
Published date: 2002
Keywords:
infrared absorption spectroscopy, vibrations of adsorbed molecules, carbon monoxide, platinum, vibrational phase relaxation, dipole-forbidden modes, reflection-absorption, system pt(111)-co, spectroscopy, stretch, surfaces
Identifiers
Local EPrints ID: 19862
URI: http://eprints.soton.ac.uk/id/eprint/19862
ISSN: 0039-6028
PURE UUID: 03d342da-243b-4ba3-9244-8dd7cc90479f
Catalogue record
Date deposited: 22 Feb 2006
Last modified: 16 Mar 2024 02:59
Export record
Altmetrics
Contributors
Author:
Mark Surman
Author:
Patrick L. Hagans
Author:
Natalie E. Wilson
Author:
Christopher J. Baily
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
