The University of Southampton
University of Southampton Institutional Repository

Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study

Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study
Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study
Synchrotron far-IR light has allowed the rapid collection of high quality reflection-absorption infrared spectra of the metal-adsorbate stretching vibrations of CO adsorbed in atop (464 cm(-1)) and bridging (3 76 cm(-1)) sites on Pt{1 1 1} at half monolayer coverage at 260 K. In contrast to earlier reports we find no evidence for a Fermi resonance induced splitting of the absorption band assigned to the bridge bonded species.
infrared absorption spectroscopy, vibrations of adsorbed molecules, carbon monoxide, platinum, vibrational phase relaxation, dipole-forbidden modes, reflection-absorption, system pt(111)-co, spectroscopy, stretch, surfaces
0039-6028
L303-L306
Surman, Mark
fbb90d91-1a9e-473e-a603-5fdd53459375
Hagans, Patrick L.
ddee1ce7-3f80-43f4-9900-ba6de7c6fbbe
Wilson, Natalie E.
15d9ac4a-5da3-4f41-ac2b-196b06607746
Baily, Christopher J.
9ca8e7be-d044-47ea-955a-7ab8ce4754fe
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
Surman, Mark
fbb90d91-1a9e-473e-a603-5fdd53459375
Hagans, Patrick L.
ddee1ce7-3f80-43f4-9900-ba6de7c6fbbe
Wilson, Natalie E.
15d9ac4a-5da3-4f41-ac2b-196b06607746
Baily, Christopher J.
9ca8e7be-d044-47ea-955a-7ab8ce4754fe
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169

Surman, Mark, Hagans, Patrick L., Wilson, Natalie E., Baily, Christopher J. and Russell, Andrea E. (2002) Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study. Surface Science, 511 (1-3), L303-L306. (doi:10.1016/S0039-6028(02)01565-0).

Record type: Article

Abstract

Synchrotron far-IR light has allowed the rapid collection of high quality reflection-absorption infrared spectra of the metal-adsorbate stretching vibrations of CO adsorbed in atop (464 cm(-1)) and bridging (3 76 cm(-1)) sites on Pt{1 1 1} at half monolayer coverage at 260 K. In contrast to earlier reports we find no evidence for a Fermi resonance induced splitting of the absorption band assigned to the bridge bonded species.

This record has no associated files available for download.

More information

Published date: 2002
Keywords: infrared absorption spectroscopy, vibrations of adsorbed molecules, carbon monoxide, platinum, vibrational phase relaxation, dipole-forbidden modes, reflection-absorption, system pt(111)-co, spectroscopy, stretch, surfaces

Identifiers

Local EPrints ID: 19862
URI: http://eprints.soton.ac.uk/id/eprint/19862
ISSN: 0039-6028
PURE UUID: 03d342da-243b-4ba3-9244-8dd7cc90479f
ORCID for Andrea E. Russell: ORCID iD orcid.org/0000-0002-8382-6443

Catalogue record

Date deposited: 22 Feb 2006
Last modified: 09 Jan 2022 02:56

Export record

Altmetrics

Contributors

Author: Mark Surman
Author: Patrick L. Hagans
Author: Natalie E. Wilson
Author: Christopher J. Baily

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×