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An efficient synthesis of endo,exo-furofuranone derivatives

An efficient synthesis of endo,exo-furofuranone derivatives
An efficient synthesis of endo,exo-furofuranone derivatives
The ring openings of 1-acetyl-4-phenyl-3-oxabicyclo[3.1.0]hexane afforded alpha-acetyl-gamma-butyrolactones that underwent a novel diazo-transfer reaction, followed by C-H insertion, to provide a series of endo, exo-furofuranone analogues.
metal carbene transformations, organic-synthesis, carbonyl-compounds, (+/-)-epimagnolin-a, cyclization
1359-7345
2042-2043
Swain, N. A.
c7cedfa8-85df-4a02-84f9-9fbcacdc5e6b
Brown, R. C. D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Bruton, G.
1d7856c4-3439-4b95-a045-25fda1ccd47d
Swain, N. A.
c7cedfa8-85df-4a02-84f9-9fbcacdc5e6b
Brown, R. C. D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Bruton, G.
1d7856c4-3439-4b95-a045-25fda1ccd47d

Swain, N. A., Brown, R. C. D. and Bruton, G. (2002) An efficient synthesis of endo,exo-furofuranone derivatives. Chemical Communications, (18), 2042-2043. (doi:10.1039/b206150c).

Record type: Article

Abstract

The ring openings of 1-acetyl-4-phenyl-3-oxabicyclo[3.1.0]hexane afforded alpha-acetyl-gamma-butyrolactones that underwent a novel diazo-transfer reaction, followed by C-H insertion, to provide a series of endo, exo-furofuranone analogues.

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More information

Published date: 2002
Keywords: metal carbene transformations, organic-synthesis, carbonyl-compounds, (+/-)-epimagnolin-a, cyclization

Identifiers

Local EPrints ID: 19863
URI: http://eprints.soton.ac.uk/id/eprint/19863
ISSN: 1359-7345
PURE UUID: f54d4315-17ab-45a4-8515-73a928a4374c
ORCID for R. C. D. Brown: ORCID iD orcid.org/0000-0003-0156-7087

Catalogue record

Date deposited: 21 Feb 2006
Last modified: 28 Apr 2022 01:41

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Contributors

Author: N. A. Swain
Author: R. C. D. Brown ORCID iD
Author: G. Bruton

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