Akutsu-Sato, Akane, Akutsu, Hiroki, Turner, Scott S., Le Pevelen, Delphine, Day, Peter, Light, Mark E., Hursthouse, Michael B., Akutagawa, Tomoyuki and Nakamura, Takayoshi
Structures and physical properties of BEDT-TTF salts containing channels of protons
Synthetic Metals, 135-136, (1-3), . (doi:10.1016/S0379-6779(02)00781-6).
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Charge transfer salts with stoichiometry ?''-(BEDT-TTF)(4)[M(C2O4)(3)](18-crown-6 ether)(9H(x)O), where M = Cr, Ga or Fe and x = 2 or 3 are reported. Their structures suggest that proton migration is possible. Variable temperature resistivity measurements on the Cr salt show metallic behaviour down to 180K. Magnetic susceptibility of the Cr salt is paramagnetic down to 1.8 K. Preliminary impedance measurements suggest that the proton conductivities of the Cr and Ga salts are the order of 10(-3) S cm(-1) at 300 K.
|Digital Object Identifier (DOI):
||Proceedings of the International Conference on Science and Technology of Synthetic Metals
||organic conductors based on radical cation salts
|4 April 2003||Published|
||23 Feb 2006
||16 Apr 2017 23:00
|Further Information:||Google Scholar|
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