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Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex
Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex
The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented "double" charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.
paramagnetic resonance, electronic-structure, adducts, triiodide, chains
0020-1669
3975-3977
Allen, David W.
4cbcd21b-4bb9-40e8-baa9-27b1b3e5a7b2
Berridge, Rory
6aa42596-b293-4914-a1eb-2a974e7f2ed4
Bricklebank, Neil
6e082c98-a747-4690-bb37-f05f24d621f5
Forder, Susan D.
5f7acb93-e49b-460f-a113-b68d869fce7d
Palacio, Fernando
2e79bf84-8302-4d7f-92c5-167c7e89e9f1
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Skabara, Peter J.
7138e414-7d50-41c7-933e-0bccad2fa4cd
Allen, David W.
4cbcd21b-4bb9-40e8-baa9-27b1b3e5a7b2
Berridge, Rory
6aa42596-b293-4914-a1eb-2a974e7f2ed4
Bricklebank, Neil
6e082c98-a747-4690-bb37-f05f24d621f5
Forder, Susan D.
5f7acb93-e49b-460f-a113-b68d869fce7d
Palacio, Fernando
2e79bf84-8302-4d7f-92c5-167c7e89e9f1
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Skabara, Peter J.
7138e414-7d50-41c7-933e-0bccad2fa4cd

Allen, David W., Berridge, Rory, Bricklebank, Neil, Forder, Susan D., Palacio, Fernando, Coles, Simon J., Hursthouse, Michael B. and Skabara, Peter J. (2003) Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. Inorganic Chemistry, 42 (13), 3975-3977. (doi:10.1021/ic034092f).

Record type: Article

Abstract

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented "double" charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

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More information

Published date: 30 June 2003
Keywords: paramagnetic resonance, electronic-structure, adducts, triiodide, chains

Identifiers

Local EPrints ID: 19879
URI: https://eprints.soton.ac.uk/id/eprint/19879
ISSN: 0020-1669
PURE UUID: 274d35ec-49e5-439f-bc0b-ef7a697d05e2
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 23 Feb 2006
Last modified: 19 Jul 2019 01:06

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