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Reactivity of 2-methyl thioisomunchnone with acid chlorides

Record type: Article

This work describes the reactivity of 2-alkyl thioisomunchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomunchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.

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Citation

Avalos, M., Babiano, R., Cintas, P., Diaz, J., Hursthouse, M. B., Jimenez, J. L., Light, M. E., Lopez, I. and Palacios, J. C. (2003) Reactivity of 2-methyl thioisomunchnone with acid chlorides Tetrahedron Letters, 44, (25), pp. 4657-4660. (doi:10.1016/S0040-4039(03)01087-6).

More information

Published date: 16 June 2003
Keywords: cycloadditions, 1, 3-dicarbonyl compounds, mesoionics, tautomerism, thioisomunchnonesmesoionic compounds, derivatives, systems

Identifiers

Local EPrints ID: 19883
URI: http://eprints.soton.ac.uk/id/eprint/19883
ISSN: 0040-4039
PURE UUID: 5759255e-de76-4219-b8ee-2ae5e0afbc05
ORCID for M. E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 17 Jul 2017 16:30

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Contributors

Author: M. Avalos
Author: R. Babiano
Author: P. Cintas
Author: J. Diaz
Author: J. L. Jimenez
Author: M. E. Light ORCID iD
Author: I. Lopez
Author: J. C. Palacios

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