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Reactivity of 2-methyl thioisomunchnone with acid chlorides

Avalos, M., Babiano, R., Cintas, P., Diaz, J., Hursthouse, M. B., Jimenez, J. L., Light, M. E., Lopez, I. and Palacios, J. C. (2003) Reactivity of 2-methyl thioisomunchnone with acid chlorides Tetrahedron Letters, 44, (25), pp. 4657-4660. (doi:10.1016/S0040-4039(03)01087-6).

Record type: Article


This work describes the reactivity of 2-alkyl thioisomunchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomunchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.

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Published date: 16 June 2003
Keywords: cycloadditions, 1, 3-dicarbonyl compounds, mesoionics, tautomerism, thioisomunchnonesmesoionic compounds, derivatives, systems


Local EPrints ID: 19883
ISSN: 0040-4039
PURE UUID: 5759255e-de76-4219-b8ee-2ae5e0afbc05
ORCID for M. E. Light: ORCID iD

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Date deposited: 17 Feb 2006
Last modified: 17 Jul 2017 16:30

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Author: M. Avalos
Author: R. Babiano
Author: P. Cintas
Author: J. Diaz
Author: J. L. Jimenez
Author: M. E. Light ORCID iD
Author: I. Lopez
Author: J. C. Palacios

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