Avalos, M., Babiano, R., Cintas, P., Diaz, J., Hursthouse, M. B., Jimenez, J. L., Light, M. E., Lopez, I. and Palacios, J. C.
Reactivity of 2-methyl thioisomunchnone with acid chlorides
Tetrahedron Letters, 44, (25), . (doi:10.1016/S0040-4039(03)01087-6).
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This work describes the reactivity of 2-alkyl thioisomunchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomunchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.
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