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Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry

Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry
Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry
The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.
liverwort odontoschisma-denudatum, lithium chloroallylide, tandem insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones
1359-7345
2786-2787
Baldwin, I.R.
ad5cd11b-3fa2-475d-92dc-d5ced10f8779
Whitby, R.J.
45632236-ab00-4ad0-a02d-6209043e818b
Baldwin, I.R.
ad5cd11b-3fa2-475d-92dc-d5ced10f8779
Whitby, R.J.
45632236-ab00-4ad0-a02d-6209043e818b

Baldwin, I.R. and Whitby, R.J. (2003) Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry. Chemical Communications, 2003 (22), 2786-2787. (doi:10.1039/b309848f).

Record type: Article

Abstract

The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.

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More information

Published date: 2003
Keywords: liverwort odontoschisma-denudatum, lithium chloroallylide, tandem insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones

Identifiers

Local EPrints ID: 19886
URI: http://eprints.soton.ac.uk/id/eprint/19886
ISSN: 1359-7345
PURE UUID: 99168c4c-93fe-4b84-8493-509645ef4adb
ORCID for R.J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 21 Feb 2006
Last modified: 09 Jan 2022 02:33

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Contributors

Author: I.R. Baldwin
Author: R.J. Whitby ORCID iD

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