Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry
Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry
The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.
liverwort odontoschisma-denudatum, lithium chloroallylide, tandem
insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones
2786-2787
Baldwin, I.R.
ad5cd11b-3fa2-475d-92dc-d5ced10f8779
Whitby, R.J.
45632236-ab00-4ad0-a02d-6209043e818b
2003
Baldwin, I.R.
ad5cd11b-3fa2-475d-92dc-d5ced10f8779
Whitby, R.J.
45632236-ab00-4ad0-a02d-6209043e818b
Baldwin, I.R. and Whitby, R.J.
(2003)
Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry.
Chemical Communications, 2003 (22), .
(doi:10.1039/b309848f).
Abstract
The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.
This record has no associated files available for download.
More information
Published date: 2003
Keywords:
liverwort odontoschisma-denudatum, lithium chloroallylide, tandem
insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones
Identifiers
Local EPrints ID: 19886
URI: http://eprints.soton.ac.uk/id/eprint/19886
ISSN: 1359-7345
PURE UUID: 99168c4c-93fe-4b84-8493-509645ef4adb
Catalogue record
Date deposited: 21 Feb 2006
Last modified: 16 Mar 2024 02:33
Export record
Altmetrics
Contributors
Author:
I.R. Baldwin
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
