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Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry

Baldwin, I.R. and Whitby, R.J. (2003) Total synthesis of (+/-)-acetoxyodontoschismenol using zirconium chemistry Chemical Communications, 2003, (22), pp. 2786-2787. (doi:10.1039/b309848f).

Record type: Article


The dolabellane diterpene (+/-)-acetoxyodontoschismenol has been synthesised for the first time by a short route in which a three component coupling on zirconium is used to assemble all the carbons needed for the skeleton in one-pot.

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Published date: 2003
Keywords: liverwort odontoschisma-denudatum, lithium chloroallylide, tandem insertion, dolabellane, zirconacyclopentanes, (+/-)-delta-araneosene, construction, diterpenoids, aldehydes, ketones


Local EPrints ID: 19886
ISSN: 1359-7345
PURE UUID: 99168c4c-93fe-4b84-8493-509645ef4adb
ORCID for R.J. Whitby: ORCID iD

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Date deposited: 21 Feb 2006
Last modified: 17 Jul 2017 16:30

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Author: I.R. Baldwin
Author: R.J. Whitby ORCID iD

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