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Site-site interactions within high-loading PAMAM dendrimer resin beads

Site-site interactions within high-loading PAMAM dendrimer resin beads
Site-site interactions within high-loading PAMAM dendrimer resin beads
Combinatorial chemistry and solid-phase synthesis have revolutionised the process of drug discovery in the last decade. Ever since the concept of split and mix synthesis was introduced in 1988, and in particular the concept of one bead one compound, this approach has been associated with the possibility of generating thousands or millions of compounds in only a relatively small number of synthetic steps. The demand for high loading resins has therefore increased over the last few years. Our research has focussed on bead-loading enhancement via a dendrimerisation process. Dendrimer resin beads have shown compatibility for many chemical conditions, however high functional group density could produce undesirable site-site interactions.
solid-phase synthesis, dendrimer resin, site-site interactions solid-phase synthesis, organic-synthesis, ethers
0040-4039
2699-2702
Basso, A.
9cdcd616-ad0c-431a-b3f3-f39343a63694
Bradley, M.
078a34d6-96c4-4ce1-9aa1-454d9ee0030d
Basso, A.
9cdcd616-ad0c-431a-b3f3-f39343a63694
Bradley, M.
078a34d6-96c4-4ce1-9aa1-454d9ee0030d

Basso, A. and Bradley, M. (2003) Site-site interactions within high-loading PAMAM dendrimer resin beads. Tetrahedron Letters, 44 (13), 2699-2702. (doi:10.1016/S0040-4039(03)00374-5).

Record type: Article

Abstract

Combinatorial chemistry and solid-phase synthesis have revolutionised the process of drug discovery in the last decade. Ever since the concept of split and mix synthesis was introduced in 1988, and in particular the concept of one bead one compound, this approach has been associated with the possibility of generating thousands or millions of compounds in only a relatively small number of synthetic steps. The demand for high loading resins has therefore increased over the last few years. Our research has focussed on bead-loading enhancement via a dendrimerisation process. Dendrimer resin beads have shown compatibility for many chemical conditions, however high functional group density could produce undesirable site-site interactions.

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More information

Published date: 24 March 2003
Keywords: solid-phase synthesis, dendrimer resin, site-site interactions solid-phase synthesis, organic-synthesis, ethers

Identifiers

Local EPrints ID: 19895
URI: http://eprints.soton.ac.uk/id/eprint/19895
ISSN: 0040-4039
PURE UUID: d485a63d-7343-4e54-97aa-94d2d1bf7d70

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 15 Mar 2024 06:20

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Contributors

Author: A. Basso
Author: M. Bradley

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