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A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O

Record type: Article

The title compound, C18H2BF15O.H2O.C2H6O2, obtained by crystallization of a product formed from a reaction mixture containing B(C6F5)(3) and Me2SO2 (and H2O) in hexane, was characterized in the solid state as a supramolecular assembly containing water adducts of tris( pentafluorophenyl) borane, (H2O) B(C6F5)(3), linked together by a network of hydrogen bonds involving one additional H2O and one additional Me2SO2 molecule per adduct molecule.

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Citation

Coles, S. J., Hursthouse, M. B., Beckett, M. A. and Dutton, M. (2003) A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O Acta Crystallographica Section E: Structure Reports Online, 59, O1354-O1356. (doi:10.1107/S1600536803014065).

More information

Published date: 1 September 2003
Keywords: molecular-structure, crystal, tris(pentafluorophenyl)borane, adducts, h2o-center-dot-b(c6f5)(3), complexes

Identifiers

Local EPrints ID: 19932
URI: http://eprints.soton.ac.uk/id/eprint/19932
PURE UUID: ea72584b-cd27-4cb6-8799-23fbb60dbaa5
ORCID for S. J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 23 Feb 2006
Last modified: 17 Jul 2017 16:30

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Contributors

Author: S. J. Coles ORCID iD
Author: M. A. Beckett
Author: M. Dutton

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