A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O
A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O
The title compound, C18H2BF15O.H2O.C2H6O2, obtained by crystallization of a product formed from a reaction mixture containing B(C6F5)(3) and Me2SO2 (and H2O) in hexane, was characterized in the solid state as a supramolecular assembly containing water adducts of tris( pentafluorophenyl) borane, (H2O) B(C6F5)(3), linked together by a network of hydrogen bonds involving one additional H2O and one additional Me2SO2 molecule per adduct molecule.
molecular-structure, crystal, tris(pentafluorophenyl)borane, adducts, h2o-center-dot-b(c6f5)(3), complexes
O1354-O1356
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, M. A.
42da77d2-c5b1-4050-8e68-42c0cccb82fb
Dutton, M.
d8aa2226-9e82-4457-8b16-70b8fa00378e
1 September 2003
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, M. A.
42da77d2-c5b1-4050-8e68-42c0cccb82fb
Dutton, M.
d8aa2226-9e82-4457-8b16-70b8fa00378e
Coles, S. J., Hursthouse, M. B., Beckett, M. A. and Dutton, M.
(2003)
A supramolecular assembly: apuatris-(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)(3)center dot Me2SO2 center dot H2O.
Acta Crystallographica Section E: Structure Reports Online, 59, .
(doi:10.1107/S1600536803014065).
Abstract
The title compound, C18H2BF15O.H2O.C2H6O2, obtained by crystallization of a product formed from a reaction mixture containing B(C6F5)(3) and Me2SO2 (and H2O) in hexane, was characterized in the solid state as a supramolecular assembly containing water adducts of tris( pentafluorophenyl) borane, (H2O) B(C6F5)(3), linked together by a network of hydrogen bonds involving one additional H2O and one additional Me2SO2 molecule per adduct molecule.
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Published date: 1 September 2003
Keywords:
molecular-structure, crystal, tris(pentafluorophenyl)borane, adducts, h2o-center-dot-b(c6f5)(3), complexes
Identifiers
Local EPrints ID: 19932
URI: http://eprints.soton.ac.uk/id/eprint/19932
PURE UUID: ea72584b-cd27-4cb6-8799-23fbb60dbaa5
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Date deposited: 23 Feb 2006
Last modified: 16 Mar 2024 03:05
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Author:
M. A. Beckett
Author:
M. Dutton
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