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Synthesis and structures of potassium bisdithiocarbamate salts

Synthesis and structures of potassium bisdithiocarbamate salts
Synthesis and structures of potassium bisdithiocarbamate salts
Two structurally related dipotassium bisdithiocarbamate salts: K2[(S2CNRCH2)2](EtOH)2; R = Me, i-Pr, were synthesised from the corresponding diamines. X-ray structure determinations were performed on single crystals grown from ethanolic solutions. The different alkyl substituents have a profound affect upon the solid-state structures, with the methyl derivative possessing a complex a 3-D network and the isopropyl derivative a 2-D lamellar structure.
dithiocarbamate, potassium, steric effects, crystal structure
0044-2313
192-194
Cook, David A.
0fca0ffb-eef4-422f-b513-ce9a1f7de7cc
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Cook, David A.
0fca0ffb-eef4-422f-b513-ce9a1f7de7cc
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192

Cook, David A., Coles, Simon J., Hursthouse, Michael B. and Price, Daniel J. (2003) Synthesis and structures of potassium bisdithiocarbamate salts. Zeitschrift für anorganische und allgemeine Chemie, 629 (2), 192-194. (doi:10.1002/zaac.200390030).

Record type: Article

Abstract

Two structurally related dipotassium bisdithiocarbamate salts: K2[(S2CNRCH2)2](EtOH)2; R = Me, i-Pr, were synthesised from the corresponding diamines. X-ray structure determinations were performed on single crystals grown from ethanolic solutions. The different alkyl substituents have a profound affect upon the solid-state structures, with the methyl derivative possessing a complex a 3-D network and the isopropyl derivative a 2-D lamellar structure.

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More information

Published date: 2003
Keywords: dithiocarbamate, potassium, steric effects, crystal structure
Organisations: Chemistry

Identifiers

Local EPrints ID: 19933
URI: http://eprints.soton.ac.uk/id/eprint/19933
ISSN: 0044-2313
PURE UUID: cb41907f-3383-46d2-ada5-470aedb1158a
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 24 Feb 2006
Last modified: 09 Jan 2022 02:59

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Contributors

Author: David A. Cook
Author: Simon J. Coles ORCID iD
Author: Daniel J. Price

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