Temperature dependence of tribological properties of MoS2 and MoSe2 coatings

Kubart, T., Polcar, T., Kopecky, L., Novak, R. and Novakova, D. (2005) Temperature dependence of tribological properties of MoS2 and MoSe2 coatings. Surface and Coatings Technology, 193 (1-3), 230-233. (doi:10.1016/j.surfcoat.2004.08.146).

Abstract

Transition metal dichalcogenides are well known for their lubricating properties. MoS2 is the most popular member of this family and it is widely used as a solid lubricant in vacuum and inert gases. However, the lubricating properties of MoS2 are deteriorated in humid air. It is known that molybdenum diselenide (MoSe2) has the same crystal structure and also exhibits suitable lubricating properties, but their dependence on air humidity has not been studied yet in details.

This paper is aimed to the comparison of tribological properties of MoS2 and MoSe2 coatings measured in air of different humidity and at elevated temperatures. Both coatings were prepared by non-reactive DC magnetron sputtering and tested with ball-on-disc high temperature tribometer. The results of measurements of friction coefficient and wear rate vs. tribometer revolutions and the resulting dependencies of friction coefficient and wear rate on ambient air relative humidity are presented.

These results show that the friction coefficient of MoSe2 was not influenced by air humidity. Wear rate of MoSe2 in dry air was substantially higher than that of MoS2; in humid air, the MoS2 wear rate increased rapidly while wear rate of MoSe2 remained unchanged. The operating temperature of both coatings was limited to 350 °C

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Contributors

Author: T. Polcar

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