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Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT study

Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT study
Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT study
The first authenticated example of migration of a methyl group from palladium(II) to a coordinated N-heterocyclic carbene is described.
oxidative-addition, reductive elimination, exchange, pd
1359-7345
756-757
Danopoulos, A.A.
b3cd9aa6-4a49-45d8-8cb6-72b1d2a441a7
Tsoureas, N.
32b90c51-c74e-41a0-b03b-ba525d861073
Green, J.C.
072f0b7f-145c-4646-a2ca-d943a8fbe86b
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Danopoulos, A.A.
b3cd9aa6-4a49-45d8-8cb6-72b1d2a441a7
Tsoureas, N.
32b90c51-c74e-41a0-b03b-ba525d861073
Green, J.C.
072f0b7f-145c-4646-a2ca-d943a8fbe86b
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Danopoulos, A.A., Tsoureas, N., Green, J.C. and Hursthouse, M.B. (2003) Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT study. Chemical Communications, 2003 (6), 756-757. (doi:10.1039/b212453j).

Record type: Article

Abstract

The first authenticated example of migration of a methyl group from palladium(II) to a coordinated N-heterocyclic carbene is described.

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More information

Published date: 2003
Keywords: oxidative-addition, reductive elimination, exchange, pd

Identifiers

Local EPrints ID: 19940
URI: https://eprints.soton.ac.uk/id/eprint/19940
ISSN: 1359-7345
PURE UUID: 657a548e-1678-4a3b-9290-6631662bc225

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Date deposited: 21 Feb 2006
Last modified: 15 Jul 2019 19:26

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Contributors

Author: A.A. Danopoulos
Author: N. Tsoureas
Author: J.C. Green
Author: M.B. Hursthouse

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