Sulfur-mediated radical cyclisation reactions on solid support
Sulfur-mediated radical cyclisation reactions on solid support
Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.
cyclization reaction, oxime ethers, disulfide, esters, thiols
503-506
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
May, P. J.
14df24ea-ca00-4041-a752-dd15e8404a14
Bradley, M.
078a34d6-96c4-4ce1-9aa1-454d9ee0030d
13 January 2003
Harrowven, D. C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
May, P. J.
14df24ea-ca00-4041-a752-dd15e8404a14
Bradley, M.
078a34d6-96c4-4ce1-9aa1-454d9ee0030d
Harrowven, D. C., May, P. J. and Bradley, M.
(2003)
Sulfur-mediated radical cyclisation reactions on solid support.
Tetrahedron Letters, 44 (3), .
(doi:10.1016/S0040-4039(02)02594-7).
Abstract
Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.
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Published date: 13 January 2003
Keywords:
cyclization reaction, oxime ethers, disulfide, esters, thiols
Identifiers
Local EPrints ID: 19971
URI: http://eprints.soton.ac.uk/id/eprint/19971
ISSN: 0040-4039
PURE UUID: ead6ec7c-5523-49c9-a66e-79b3fc748c27
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Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 02:46
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Author:
P. J. May
Author:
M. Bradley
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