Sulfur-mediated radical cyclisation reactions on solid support


Harrowven, D. C., May, P. J. and Bradley, M. (2003) Sulfur-mediated radical cyclisation reactions on solid support Tetrahedron Letters, 44, (3), pp. 503-506. (doi:10.1016/S0040-4039(02)02594-7).

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Description/Abstract

Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(02)02594-7
ISSNs: 0040-4039 (print)
Keywords: cyclization reaction, oxime ethers, disulfide, esters, thiols
Subjects:
ePrint ID: 19971
Date :
Date Event
13 January 2003Published
Date Deposited: 20 Feb 2006
Last Modified: 16 Apr 2017 23:00
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19971

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