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Sulfur-mediated radical cyclisation reactions on solid support

Harrowven, D. C., May, P. J. and Bradley, M. (2003) Sulfur-mediated radical cyclisation reactions on solid support Tetrahedron Letters, 44, (3), pp. 503-506. (doi:10.1016/S0040-4039(02)02594-7).

Record type: Article


Two methods for effecting radical cyclisation reactions of solid-supported 1,6-dienes are described. Additions of thiophenol and p-tolyl benzeneselenosulfonate have each been achieved with a concomitant 5-exo-trig radical cyclisation leading to the formation of highly functionalised cyclopentanes.

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Published date: 13 January 2003
Keywords: cyclization reaction, oxime ethers, disulfide, esters, thiols


Local EPrints ID: 19971
ISSN: 0040-4039
PURE UUID: ead6ec7c-5523-49c9-a66e-79b3fc748c27

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Date deposited: 20 Feb 2006
Last modified: 17 Jul 2017 16:30

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Author: D. C. Harrowven
Author: P. J. May
Author: M. Bradley

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