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Properties of nanocomposite film combining hard TiN matrix with embedded fullerene-like WS2 nanoclusters

Properties of nanocomposite film combining hard TiN matrix with embedded fullerene-like WS2 nanoclusters
Properties of nanocomposite film combining hard TiN matrix with embedded fullerene-like WS2 nanoclusters
We have developed hard self-lubricant coatings combining a hard matrix (TiN) and a self-lubricant phase in the form of inorganic-like WS2 fullerene. The nanoparticles were injected from the preparation chamber directly to the sample surface during reactive sputtering from a Ti target in Ar/N2 atmosphere. The injection of the particles led to the local oxidation of the matrix due to the flow of residual oxygen from the preparation chamber; therefore, the final composite was TiN/Ti–O–WS2. The observation of the composite film by scanning and transmission electron microscopies showed the incorporation of the WS2 nanoparticles; however, their bonding with the matrix was weak. The analysis of the wear tracks did not show any presence of WS2 in the contact.
0040-6090
3191-3195
Polcar, T.
c669b663-3ba9-4e7b-9f97-8ef5655ac6d2
Mohan, D. Bharathi
ca23b758-aefe-4195-a3a1-769c65e77e6b
Sandu, C. Silviu
ff3cedc8-4aa4-4b4f-ab9c-91686f32064b
Radnoczi, G.
d1f8cd79-1991-442f-bebd-56c8c828615c
Cavaleiro, A.
114e42eb-7255-47ef-834d-0546d56d3171
Polcar, T.
c669b663-3ba9-4e7b-9f97-8ef5655ac6d2
Mohan, D. Bharathi
ca23b758-aefe-4195-a3a1-769c65e77e6b
Sandu, C. Silviu
ff3cedc8-4aa4-4b4f-ab9c-91686f32064b
Radnoczi, G.
d1f8cd79-1991-442f-bebd-56c8c828615c
Cavaleiro, A.
114e42eb-7255-47ef-834d-0546d56d3171

Polcar, T., Mohan, D. Bharathi, Sandu, C. Silviu, Radnoczi, G. and Cavaleiro, A. (2011) Properties of nanocomposite film combining hard TiN matrix with embedded fullerene-like WS2 nanoclusters. Thin Solid Films, 519 (10), 3191-3195. (doi:10.1016/j.tsf.2010.12.180).

Record type: Article

Abstract

We have developed hard self-lubricant coatings combining a hard matrix (TiN) and a self-lubricant phase in the form of inorganic-like WS2 fullerene. The nanoparticles were injected from the preparation chamber directly to the sample surface during reactive sputtering from a Ti target in Ar/N2 atmosphere. The injection of the particles led to the local oxidation of the matrix due to the flow of residual oxygen from the preparation chamber; therefore, the final composite was TiN/Ti–O–WS2. The observation of the composite film by scanning and transmission electron microscopies showed the incorporation of the WS2 nanoparticles; however, their bonding with the matrix was weak. The analysis of the wear tracks did not show any presence of WS2 in the contact.

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More information

Published date: 2011
Organisations: nCATS Group

Identifiers

Local EPrints ID: 199871
URI: http://eprints.soton.ac.uk/id/eprint/199871
ISSN: 0040-6090
PURE UUID: 714179b4-c94c-4468-97aa-deb48e2c3af2
ORCID for T. Polcar: ORCID iD orcid.org/0000-0002-0863-6287

Catalogue record

Date deposited: 20 Oct 2011 15:02
Last modified: 15 Mar 2024 03:40

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Contributors

Author: T. Polcar ORCID iD
Author: D. Bharathi Mohan
Author: C. Silviu Sandu
Author: G. Radnoczi
Author: A. Cavaleiro

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