Electro-coalescence of digitally controlled droplets

Niu, Xize, Gielen, Fabrice, deMello, Andrew J. and Edel, Joshua B. (2009) Electro-coalescence of digitally controlled droplets. Analytical Chemistry, 81 (17), 7321-7325. (doi:10.1021/ac901188n).

Abstract

In this paper we describe a universal mechanism for merging multiple aqueous microdroplets within a flowing stream consisting of an oil carrier phase. Our approach involves the use of both a pillar array acting as a passive merging element, as well as built-in electrodes acting as an active merging element. The pillar array enables slowing down and trapping of the droplets via the drainage of the oil phase. This brings adjacent droplets into close proximity. At this point, an electric field applied to the electrodes breaks up the thin oil film surrounding the droplets resulting in merging.

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