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A convergent regiospecific synthesis of zirconium enolates

Record type: Article

alpha-Lithiated phenylsulphonyloxiranes insert into alkenylzirconocene chlorides with loss of phenylsulphinate to give zirconyloxiranes which smoothly rearrange by either alpha- or beta- C-O cleavage to afford regiodefined zirconium enolates which may be further elaborated.

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Citation

Kasatkin, A. and Whitby, R. J. (2003) A convergent regiospecific synthesis of zirconium enolates Tetrahedron, 59, (49), pp. 9857-9864. (doi:10.1016/j.tet.2003.09.022).

More information

Published date: 1 December 2003
Keywords: zirconium enolate, carbenoid, lithiated oxirane, multicomponent, rearrangementcarbenoid insertion, oxiranyl anions, epoxides, rearrangement, chemistry, reagents, zirconacycles, derivatives, alkylation, mechanism

Identifiers

Local EPrints ID: 19991
URI: http://eprints.soton.ac.uk/id/eprint/19991
ISSN: 0040-4020
PURE UUID: 80e0d97f-c578-4e2a-85cd-513ca7253124
ORCID for R. J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 17 Jul 2017 16:29

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Contributors

Author: A. Kasatkin
Author: R. J. Whitby ORCID iD

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