A convergent regiospecific synthesis of zirconium enolates

Kasatkin, A. and Whitby, R. J. (2003) A convergent regiospecific synthesis of zirconium enolates Tetrahedron, 59, (49), pp. 9857-9864. (doi:10.1016/j.tet.2003.09.022).


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alpha-Lithiated phenylsulphonyloxiranes insert into alkenylzirconocene chlorides with loss of phenylsulphinate to give zirconyloxiranes which smoothly rearrange by either alpha- or beta- C-O cleavage to afford regiodefined zirconium enolates which may be further elaborated.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/j.tet.2003.09.022
ISSNs: 0040-4020 (print)
Keywords: zirconium enolate, carbenoid, lithiated oxirane, multicomponent, rearrangementcarbenoid insertion, oxiranyl anions, epoxides, rearrangement, chemistry, reagents, zirconacycles, derivatives, alkylation, mechanism
ePrint ID: 19991
Date :
Date Event
1 December 2003Published
Date Deposited: 17 Feb 2006
Last Modified: 16 Apr 2017 23:00
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/19991

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