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UV written waveguides using crosslinkable PMMA-based copolymers

UV written waveguides using crosslinkable PMMA-based copolymers
UV written waveguides using crosslinkable PMMA-based copolymers
Crosslinkable copolymers poly(methylmethacrylate/2-methacryloylethylmethacrylate) (P(MMA/MAOEMA)) were developed for waveguide applications. P(MMA/MAOEMA) can crosslink under either UV exposure or heating. The UV-induced refractive index change in unreacted P(MMA/MAOEMA) is found to depend on-the fluence. UV exposure of thermally crosslinked P(MMA/MAOEMA) can induce further structure change and thus index change, and therefore, was found to be useful for creating the core layers in optical waveguides. The photosensitivity of the thermally crosslinked polymers is sufficient for the fabrication of low, loss (<1 dB/cm) channel waveguides in the thermally crosslinked copolymer system.
optical applications, mu-m, polymer
583-592
Koo, Jae-Sun
ac973524-e44e-41de-8062-f20460490000
Smith, Peter G.R.
8979668a-8b7a-4838-9a74-1a7cfc6665f6
Williams, Richard B.
c46c705e-6678-4591-8ea0-d25049264d63
Riziotis, Christos
84a8140d-44bb-4be4-b50d-5428087058c9
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Koo, Jae-Sun
ac973524-e44e-41de-8062-f20460490000
Smith, Peter G.R.
8979668a-8b7a-4838-9a74-1a7cfc6665f6
Williams, Richard B.
c46c705e-6678-4591-8ea0-d25049264d63
Riziotis, Christos
84a8140d-44bb-4be4-b50d-5428087058c9
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56

Koo, Jae-Sun, Smith, Peter G.R., Williams, Richard B., Riziotis, Christos and Grossel, Martin C. (2003) UV written waveguides using crosslinkable PMMA-based copolymers. Optical Materials, 23 (3-4), 583-592. (doi:10.1016/S0925-3467(03)00025-9).

Record type: Article

Abstract

Crosslinkable copolymers poly(methylmethacrylate/2-methacryloylethylmethacrylate) (P(MMA/MAOEMA)) were developed for waveguide applications. P(MMA/MAOEMA) can crosslink under either UV exposure or heating. The UV-induced refractive index change in unreacted P(MMA/MAOEMA) is found to depend on-the fluence. UV exposure of thermally crosslinked P(MMA/MAOEMA) can induce further structure change and thus index change, and therefore, was found to be useful for creating the core layers in optical waveguides. The photosensitivity of the thermally crosslinked polymers is sufficient for the fabrication of low, loss (<1 dB/cm) channel waveguides in the thermally crosslinked copolymer system.

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Published date: 1 September 2003
Keywords: optical applications, mu-m, polymer

Identifiers

Local EPrints ID: 19999
URI: http://eprints.soton.ac.uk/id/eprint/19999
PURE UUID: 8f1385f3-0823-44f9-a154-6e806f42dd9d
ORCID for Peter G.R. Smith: ORCID iD orcid.org/0000-0003-0319-718X
ORCID for Martin C. Grossel: ORCID iD orcid.org/0000-0001-7469-6854

Catalogue record

Date deposited: 24 Feb 2006
Last modified: 16 Mar 2024 02:50

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Contributors

Author: Jae-Sun Koo
Author: Peter G.R. Smith ORCID iD
Author: Richard B. Williams
Author: Christos Riziotis

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