Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide
Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide
Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.
phosphine, phosphine oxide, tin
280-282
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
15 December 2003
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, R.
ec08d4e1-fc72-4d22-9f47-2bc83a475b1c
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Levason, W., Patel, R. and Reid, G.
(2003)
Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide.
Journal of Organometallic Chemistry, 688 (1-2), .
(doi:10.1016/j.jorganchem.2003.07.025).
Abstract
Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.
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Published date: 15 December 2003
Keywords:
phosphine, phosphine oxide, tin
Identifiers
Local EPrints ID: 20021
URI: http://eprints.soton.ac.uk/id/eprint/20021
ISSN: 0022-328X
PURE UUID: 87e40d3c-a49c-403c-88a3-a06e31e84cf4
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Date deposited: 23 Feb 2006
Last modified: 16 Mar 2024 02:43
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Author:
R. Patel
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