Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide


Levason, W., Patel, R. and Reid, G. (2003) Catalytic air oxidation of tertiary arylphosphines in the presence of tin(IV) iodide Journal of Organometallic Chemistry, 688, (1-2), pp. 280-282. (doi:10.1016/j.jorganchem.2003.07.025).

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Description/Abstract

Arylphosphines including Ph3P, o-C6H4(PPh2)(2) and Ph2PCH2CH2PPh2 are cleanly and quantitatively converted into the corresponding phosphine oxides on reaction with dry air or dioxygen in CH2Cl2 solution in the presence of catalytic amounts of SnI4.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/j.jorganchem.2003.07.025
ISSNs: 0022-328X (print)
Keywords: phosphine, phosphine oxide, tin
Subjects:
ePrint ID: 20021
Date :
Date Event
15 December 2003Published
Date Deposited: 23 Feb 2006
Last Modified: 16 Apr 2017 23:00
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/20021

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