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Tris(nitrato-?² O-2,O')tris(triphenylphosphine oxide- ?O)terbium(III) acetone sesquisolvate

Tris(nitrato-?² O-2,O')tris(triphenylphosphine oxide- ?O)terbium(III) acetone sesquisolvate
Tris(nitrato-?² O-2,O')tris(triphenylphosphine oxide- ?O)terbium(III) acetone sesquisolvate
The title compound, [Tb(NO3)(3)(C18H15OP)(3)] . 1.5(CH3)(2)CO, contains discrete molecules with nine-coordinate Tb atoms, all nitrate groups being bonded as symmetrical bidentate ligands; Tb - O(P) = 2.307 (4), 2.309 (4) and 2.295 (4) Angstrom, and Tb-O( N) = 2.467 (4)- 2.539 (4) Angstrom).
complexes
M322-M323
Matthews, M.L.
7e22d0ac-e9e8-494a-a69f-af31bb12ab57
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Matthews, M.L.
7e22d0ac-e9e8-494a-a69f-af31bb12ab57
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7

Matthews, M.L. and Webster, M. (2003) Tris(nitrato-?² O-2,O')tris(triphenylphosphine oxide- ?O)terbium(III) acetone sesquisolvate. Acta Crystallographica Section E: Crystallographic Communications, 59 (6), M322-M323. (doi:10.1107/S160053680300967X).

Record type: Article

Abstract

The title compound, [Tb(NO3)(3)(C18H15OP)(3)] . 1.5(CH3)(2)CO, contains discrete molecules with nine-coordinate Tb atoms, all nitrate groups being bonded as symmetrical bidentate ligands; Tb - O(P) = 2.307 (4), 2.309 (4) and 2.295 (4) Angstrom, and Tb-O( N) = 2.467 (4)- 2.539 (4) Angstrom).

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More information

Published date: 1 June 2003
Keywords: complexes

Identifiers

Local EPrints ID: 20043
URI: http://eprints.soton.ac.uk/id/eprint/20043
PURE UUID: 27414803-5a63-4762-ac58-021efb306dfb

Catalogue record

Date deposited: 24 Feb 2006
Last modified: 15 Mar 2024 06:21

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Contributors

Author: M.L. Matthews
Author: M. Webster

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