Relativistic corrections for the vibration-rotation levels of the ground electronic state of the hydrogen molecular cation H-2(+)
Relativistic corrections for the vibration-rotation levels of the ground electronic state of the hydrogen molecular cation H-2(+)
Previous work [Moss, R. E., and Valenzano, L., 2002, Molec. Phys., 100, 649 and 1527] on the non-adiabatic properties of the vibration-rotation levels of the ground electronic state of the hydrogen molecular cation is extended to the calculation of relativistic corrections. Unlike the earlier calculations, in which all matrix elements were evaluated analytically, numerical methods are needed for some of the integrals.
transformed hamiltonian theory, hd+, ion, dissociation, spectroscopy, isotopomers, spectrum
2635-2646
Moss, R E.
5d410492-850a-4950-85fd-2deb89f60859
Valenzano, L.
5dc37261-a2d5-4d56-b7fc-059c1c4e7738
20 August 2003
Moss, R E.
5d410492-850a-4950-85fd-2deb89f60859
Valenzano, L.
5dc37261-a2d5-4d56-b7fc-059c1c4e7738
Moss, R E. and Valenzano, L.
(2003)
Relativistic corrections for the vibration-rotation levels of the ground electronic state of the hydrogen molecular cation H-2(+).
Molecular Physics, 101 (16), .
(doi:10.1080/00268970310001592683).
Abstract
Previous work [Moss, R. E., and Valenzano, L., 2002, Molec. Phys., 100, 649 and 1527] on the non-adiabatic properties of the vibration-rotation levels of the ground electronic state of the hydrogen molecular cation is extended to the calculation of relativistic corrections. Unlike the earlier calculations, in which all matrix elements were evaluated analytically, numerical methods are needed for some of the integrals.
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Published date: 20 August 2003
Keywords:
transformed hamiltonian theory, hd+, ion, dissociation, spectroscopy, isotopomers, spectrum
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Local EPrints ID: 20051
URI: http://eprints.soton.ac.uk/id/eprint/20051
ISSN: 0026-8976
PURE UUID: 7fbcfa30-27c4-4726-9780-946bc1a95da2
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Date deposited: 24 Feb 2006
Last modified: 15 Mar 2024 06:21
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Author:
R E. Moss
Author:
L. Valenzano
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