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Contrasting dynamic responses of supported Rh nanoparticles to H2S and SO2 and subsequent poisoning of NO reduction by H-2

Record type: Article

H2S induces rapid sulfidation of the Rh nanoparticles at room temperature and completely poisons NO reduction by H-2; SO2 elicits an equally rapid but subtle modification of nanoparticle structure but has little effect upon NO reduction at 523 K.

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Citation

Newton, M. A., Dent, A. J., Diaz-Moreno, S., Fiddy, S. G., Jyoti, B. and Evans, J. (2003) Contrasting dynamic responses of supported Rh nanoparticles to H2S and SO2 and subsequent poisoning of NO reduction by H-2 Chemical Communications, (15), pp. 1906-1907. (doi:10.1039/b304001a).

More information

Published date: 2003
Keywords: crystal-structure, sulfur, catalysts, absorption, surface, exafs, particles, rh/al2o3, platinum, exposure

Identifiers

Local EPrints ID: 20053
URI: http://eprints.soton.ac.uk/id/eprint/20053
ISSN: 1359-7345
PURE UUID: fcc98262-983f-43a9-9453-e74e80334911

Catalogue record

Date deposited: 22 Feb 2006
Last modified: 17 Jul 2017 16:29

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Contributors

Author: M. A. Newton
Author: A. J. Dent
Author: S. Diaz-Moreno
Author: S. G. Fiddy
Author: B. Jyoti
Author: J. Evans

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