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Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones

Patient, L., Berry, M. B., Coles, S. J., Hursthouse, M. B. and Kilburn, J. D. (2003) Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones Chemical Communications, (20), pp. 2552-2553. (doi:10.1039/b306636c).

Record type: Article


Silylated methylenecyclopropyl hydrazones on treatment with BF3.Et2O cyclise to give heterocyclic products involving a novel sequence of hydride and silyl shifts via a series of increasingly stable cationic intermediates.

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Published date: 2003
Keywords: cycloaddition, aldehydes, acylhydrazones, additions, ketones


Local EPrints ID: 20059
ISSN: 1359-7345
PURE UUID: ce6e0da8-2f15-48e5-bb9b-6f0661c8f40e
ORCID for S. J. Coles: ORCID iD

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Date deposited: 22 Feb 2006
Last modified: 17 Jul 2017 16:29

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Author: L. Patient
Author: M. B. Berry
Author: S. J. Coles ORCID iD
Author: J. D. Kilburn

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