Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones


Patient, L., Berry, M. B., Coles, S. J., Hursthouse, M. B. and Kilburn, J. D. (2003) Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones Chemical Communications, (20), pp. 2552-2553. (doi:10.1039/b306636c).

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Description/Abstract

Silylated methylenecyclopropyl hydrazones on treatment with BF3.Et2O cyclise to give heterocyclic products involving a novel sequence of hydride and silyl shifts via a series of increasingly stable cationic intermediates.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b306636c
ISSNs: 1359-7345 (print)
Related URLs:
Keywords: cycloaddition, aldehydes, acylhydrazones, additions, ketones
Subjects:
ePrint ID: 20059
Date :
Date Event
2003Published
Date Deposited: 22 Feb 2006
Last Modified: 16 Apr 2017 23:00
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/20059

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