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Functionalised and chelate heterocyclic carbene complexes of palladium; synthesis and structural studies

Functionalised and chelate heterocyclic carbene complexes of palladium; synthesis and structural studies
Functionalised and chelate heterocyclic carbene complexes of palladium; synthesis and structural studies
A series of picolyl-functionalised, [(CN) ligands act as chelates, while the methoxymethyl-and diethylcarbamoylmethyl-functions in 10, 11 and 12, respectively, are dangling. Derivatives of 5a in which the pyridine ring is substituted with electron withdrawing or bulky substituents show only minor variation of the pyridine-palladium distances.
1477-9226
699-708
Tulloch, Arran A.D.
8fe08eb4-a6f5-4ebb-b0a4-19fc745a018a
Winston, Scott
d7cc4b37-c1c0-4c11-b210-c172d21fc544
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Eastham, Graham
b5a80d7f-914e-4e5b-b3de-8e9944ca95d8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Tulloch, Arran A.D.
8fe08eb4-a6f5-4ebb-b0a4-19fc745a018a
Winston, Scott
d7cc4b37-c1c0-4c11-b210-c172d21fc544
Danopoulos, Andreas A.
4919c13e-ebe4-4456-b329-c806c8e22236
Eastham, Graham
b5a80d7f-914e-4e5b-b3de-8e9944ca95d8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Tulloch, Arran A.D., Winston, Scott, Danopoulos, Andreas A., Eastham, Graham and Hursthouse, Michael B. (2003) Functionalised and chelate heterocyclic carbene complexes of palladium; synthesis and structural studies. Dalton Transactions, (4), 699-708. (doi:10.1039/b209231j).

Record type: Article

Abstract

A series of picolyl-functionalised, [(CN) ligands act as chelates, while the methoxymethyl-and diethylcarbamoylmethyl-functions in 10, 11 and 12, respectively, are dangling. Derivatives of 5a in which the pyridine ring is substituted with electron withdrawing or bulky substituents show only minor variation of the pyridine-palladium distances.

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Published date: 2003

Identifiers

Local EPrints ID: 20093
URI: http://eprints.soton.ac.uk/id/eprint/20093
ISSN: 1477-9226
PURE UUID: 509dc87b-5317-44cf-b69a-266b36c95c1a

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Date deposited: 23 Feb 2006
Last modified: 15 Mar 2024 06:21

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Contributors

Author: Arran A.D. Tulloch
Author: Scott Winston
Author: Andreas A. Danopoulos
Author: Graham Eastham

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