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Square-pyramidal bonding of I-2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network

Square-pyramidal bonding of I-2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network
Square-pyramidal bonding of I-2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network
The reaction of di-[2]-pyridyl-disulfide (L) with diiodine in molar ratios ranging between 1 : 0.5 and 1 : 5 afforded [(HL+)(I-) . 5/2I(2)] as the only product, containing the first example of a self-assembled infinite polyiodide pseudo-cubic 3D-network featuring distorted square pyramidal I-. 5I(2) moieties at the nodes.
effective core potentials, template, networks, iodine
1466-8033
540-542
Aragoni, M. Carla
3e73ed7a-2cf7-4f5e-9359-61d6e34a6cd5
Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Devillanova, Francesco A.
a1015716-6d8a-4517-aac8-593b78e91561
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Huth, Susanne L.
b1cb7019-3459-4842-9d38-6db10f67384d
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Mancini, Annalisa
da134433-ee68-449c-9d2f-cad90b37a553
Aragoni, M. Carla
3e73ed7a-2cf7-4f5e-9359-61d6e34a6cd5
Arca, Massimiliano
f90b59f6-4dfb-471d-912e-3515e6507165
Devillanova, Francesco A.
a1015716-6d8a-4517-aac8-593b78e91561
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Huth, Susanne L.
b1cb7019-3459-4842-9d38-6db10f67384d
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Mancini, Annalisa
da134433-ee68-449c-9d2f-cad90b37a553

Aragoni, M. Carla, Arca, Massimiliano, Devillanova, Francesco A., Hursthouse, Michael B., Huth, Susanne L., Isaia, Francesco, Lippolis, Vito and Mancini, Annalisa (2004) Square-pyramidal bonding of I-2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network. CrystEngComm, 6, 540-542. (doi:10.1039/b415415k).

Record type: Article

Abstract

The reaction of di-[2]-pyridyl-disulfide (L) with diiodine in molar ratios ranging between 1 : 0.5 and 1 : 5 afforded [(HL+)(I-) . 5/2I(2)] as the only product, containing the first example of a self-assembled infinite polyiodide pseudo-cubic 3D-network featuring distorted square pyramidal I-. 5I(2) moieties at the nodes.

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More information

Published date: 18 October 2004
Keywords: effective core potentials, template, networks, iodine

Identifiers

Local EPrints ID: 20119
URI: https://eprints.soton.ac.uk/id/eprint/20119
ISSN: 1466-8033
PURE UUID: 104cb01b-f929-47bc-80ad-09050a5779e8

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Date deposited: 23 Feb 2006
Last modified: 15 Jul 2019 19:26

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Contributors

Author: M. Carla Aragoni
Author: Massimiliano Arca
Author: Francesco A. Devillanova
Author: Susanne L. Huth
Author: Francesco Isaia
Author: Vito Lippolis
Author: Annalisa Mancini

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