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The effect of surface species on the rate of H sorption into nanostructured Pd

The effect of surface species on the rate of H sorption into nanostructured Pd
The effect of surface species on the rate of H sorption into nanostructured Pd
Studies of the hydrogen region of nanostructured H-1-e Pd films in I M sulfuric acid in the presence of crystal violet, or when small amounts of Pt are deposited on to the surface, show that the adsorption of hydrogen onto the metal surface is suppressed but that at the same time the kinetics of absorption of hydrogen into the Pd to form the beta-hydride are significantly enhanced suggesting that the strongly adsorbed hydrogen on the Pd surface acts as a blocking layer for absorption of hydrogen into the Pd lattice.
liquid-crystalline phases, hydrogen sorption, electrochemical deposition, electrodes, palladium, platinum, films, dissolution, adsorption, rhodium
1463-9076
2895-2898
Bartlett, P.N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Marwan, J.
0773b54a-4b3a-41ea-ab7d-e4507fd3407e
Bartlett, P.N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Marwan, J.
0773b54a-4b3a-41ea-ab7d-e4507fd3407e

Bartlett, P.N. and Marwan, J. (2004) The effect of surface species on the rate of H sorption into nanostructured Pd. Physical Chemistry Chemical Physics, 6 (11), 2895-2898. (doi:10.1039/b404028g).

Record type: Article

Abstract

Studies of the hydrogen region of nanostructured H-1-e Pd films in I M sulfuric acid in the presence of crystal violet, or when small amounts of Pt are deposited on to the surface, show that the adsorption of hydrogen onto the metal surface is suppressed but that at the same time the kinetics of absorption of hydrogen into the Pd to form the beta-hydride are significantly enhanced suggesting that the strongly adsorbed hydrogen on the Pd surface acts as a blocking layer for absorption of hydrogen into the Pd lattice.

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Published date: 7 June 2004
Keywords: liquid-crystalline phases, hydrogen sorption, electrochemical deposition, electrodes, palladium, platinum, films, dissolution, adsorption, rhodium

Identifiers

Local EPrints ID: 20125
URI: http://eprints.soton.ac.uk/id/eprint/20125
ISSN: 1463-9076
PURE UUID: 87f82e87-9673-4ddd-8202-55e9572e934f
ORCID for P.N. Bartlett: ORCID iD orcid.org/0000-0002-7300-6900

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Date deposited: 22 Feb 2006
Last modified: 20 Jul 2019 01:22

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Contributors

Author: P.N. Bartlett ORCID iD
Author: J. Marwan

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