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Ferrocenylmethylphosphines ligands in the palladium-catalysed synthesis of methyl propionate

Ferrocenylmethylphosphines ligands in the palladium-catalysed synthesis of methyl propionate
Ferrocenylmethylphosphines ligands in the palladium-catalysed synthesis of methyl propionate
The synthesis of a range of novel ferrocenylmethylphosphanes ligands is described which have direct application in the palladium catalysed reaction of carbon monoxide, methanol and ethene to obtain methyl propionate, a key intermediate in the preparation of methylmethacrylate.
ferrocene, catalyst, methacrylate, ligand symmetrically disubstituted ferrocenes, carbon-monoxide, ethene, methoxycarbonylation, complexes, phosphine, hydrogenation, diethylzinc, derivatives, dppomf
1049-1052
Butler, Ian R.
a3e83fb2-442a-47c7-95c8-756a9a5e9f79
Baker, Paul K.
dc4c054f-e73f-43b8-bde8-604b4c216d25
Eastham, Graham R.
b29084e1-856b-48a4-93fc-19056065d9e7
Fortune, Kevin M.
67a13a74-0bd3-4857-af05-1287465d05e7
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Butler, Ian R.
a3e83fb2-442a-47c7-95c8-756a9a5e9f79
Baker, Paul K.
dc4c054f-e73f-43b8-bde8-604b4c216d25
Eastham, Graham R.
b29084e1-856b-48a4-93fc-19056065d9e7
Fortune, Kevin M.
67a13a74-0bd3-4857-af05-1287465d05e7
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Butler, Ian R., Baker, Paul K., Eastham, Graham R., Fortune, Kevin M., Horton, Peter N. and Hursthouse, Michael B. (2004) Ferrocenylmethylphosphines ligands in the palladium-catalysed synthesis of methyl propionate. Inorganic Chemistry Communications, 7 (9), 1049-1052. (doi:10.1016/j.inoche.2004.07.009).

Record type: Article

Abstract

The synthesis of a range of novel ferrocenylmethylphosphanes ligands is described which have direct application in the palladium catalysed reaction of carbon monoxide, methanol and ethene to obtain methyl propionate, a key intermediate in the preparation of methylmethacrylate.

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More information

Published date: 1 September 2004
Keywords: ferrocene, catalyst, methacrylate, ligand symmetrically disubstituted ferrocenes, carbon-monoxide, ethene, methoxycarbonylation, complexes, phosphine, hydrogenation, diethylzinc, derivatives, dppomf

Identifiers

Local EPrints ID: 20152
URI: https://eprints.soton.ac.uk/id/eprint/20152
PURE UUID: eda07238-58bc-4f17-8495-ec386b4c7e48
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 22 Feb 2006
Last modified: 20 Jul 2019 01:08

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