Hydrates of tin tetrachloride
Hydrates of tin tetrachloride
The crystal structures of the tri- and tetrahydrate of tin tetrachloride, viz. diaquatetrachlorotin(IV) monohydrate, [SnCl4(H2O)(2)].H2O, and diaquatetrachlorotin(IV) dihydrate, [SnCl4(H2O)(2)].2H(2)O, are reported and shown to contain the cis-[SnCl4(H2O)(2)] species and water molecules in both cases. The trihydrate contains chains of the tin species linked by a single hydrogen-bonded water molecule, whilst the tetrahydrate has a three-dimensional network. In addition, there are O-H...Cl interactions present.
complexes
I47-I49
Genge, Anthony R.J.
152b429b-c1ca-4e7f-b463-b017d0d4ca4e
Levason, William
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Patel, Rina
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Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
1 April 2004
Genge, Anthony R.J.
152b429b-c1ca-4e7f-b463-b017d0d4ca4e
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, Rina
0f4f5122-ade3-4523-8c7c-a7792a884692
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Genge, Anthony R.J., Levason, William, Patel, Rina, Reid, Gillian and Webster, Michael
(2004)
Hydrates of tin tetrachloride.
Acta Crystallographica Section C: Crystal Structure Communications, 60 (4), .
(doi:10.1107/S0108270104005633).
Abstract
The crystal structures of the tri- and tetrahydrate of tin tetrachloride, viz. diaquatetrachlorotin(IV) monohydrate, [SnCl4(H2O)(2)].H2O, and diaquatetrachlorotin(IV) dihydrate, [SnCl4(H2O)(2)].2H(2)O, are reported and shown to contain the cis-[SnCl4(H2O)(2)] species and water molecules in both cases. The trihydrate contains chains of the tin species linked by a single hydrogen-bonded water molecule, whilst the tetrahydrate has a three-dimensional network. In addition, there are O-H...Cl interactions present.
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Published date: 1 April 2004
Keywords:
complexes
Identifiers
Local EPrints ID: 20210
URI: http://eprints.soton.ac.uk/id/eprint/20210
ISSN: 0108-2701
PURE UUID: 501692b0-431c-4daa-88a8-e03422eabd69
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Date deposited: 21 Feb 2006
Last modified: 16 Mar 2024 02:43
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Contributors
Author:
Anthony R.J. Genge
Author:
Rina Patel
Author:
Michael Webster
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