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Unusual structural trends in the MCl3( 8 aneSe(2)) (M = As, Sb, Bi) adducts

Unusual structural trends in the MCl3( 8 aneSe(2)) (M = As, Sb, Bi) adducts
Unusual structural trends in the MCl3( 8 aneSe(2)) (M = As, Sb, Bi) adducts
The structures of the homologous [MCl3([8]aneSe(2))] ( M = As, Sb or Bi; [8] aneSe(2) = 1,5-diselenacyclooctane) ladder structures formed from planar M2Cl6 units linked by selenoether ligands with trans Se atoms reveal unexpected structural patterns - possible reasons for these are discussed.
antimony(iii) halide-complexes, seleno-ether ligands, thio-ether, coordination, thioether, chemistry
1477-9226
980-981
Hill, Nicholas J.
c588ad7e-5668-46b9-b84a-791b664f37aa
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, Rina
0f4f5122-ade3-4523-8c7c-a7792a884692
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Hill, Nicholas J.
c588ad7e-5668-46b9-b84a-791b664f37aa
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Patel, Rina
0f4f5122-ade3-4523-8c7c-a7792a884692
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7

Hill, Nicholas J., Levason, William, Patel, Rina, Reid, Gillian and Webster, Michael (2004) Unusual structural trends in the MCl3( 8 aneSe(2)) (M = As, Sb, Bi) adducts. Dalton Transactions, (7), 980-981. (doi:10.1039/b401384k).

Record type: Article

Abstract

The structures of the homologous [MCl3([8]aneSe(2))] ( M = As, Sb or Bi; [8] aneSe(2) = 1,5-diselenacyclooctane) ladder structures formed from planar M2Cl6 units linked by selenoether ligands with trans Se atoms reveal unexpected structural patterns - possible reasons for these are discussed.

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More information

Published date: 2004
Keywords: antimony(iii) halide-complexes, seleno-ether ligands, thio-ether, coordination, thioether, chemistry
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Identifiers

Local EPrints ID: 20231
URI: http://eprints.soton.ac.uk/id/eprint/20231
DOI: doi:10.1039/b401384k
ISSN: 1477-9226
PURE UUID: c1ce5c0a-d63f-49a5-b6ad-820e22b52c0a
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 21 Feb 2006
Last modified: 16 Mar 2024 02:43

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Contributors

Author: Nicholas J. Hill
Author: William Levason ORCID iD
Author: Rina Patel
Author: Gillian Reid ORCID iD
Author: Michael Webster

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