The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

Samarium diiodide coupling of enones: a remarkable cascade sequence

Samarium diiodide coupling of enones: a remarkable cascade sequence
Samarium diiodide coupling of enones: a remarkable cascade sequence
Treatment of cyclic enones with SmI2 in THF/MeOH (4:1) led to tricyclic diol products in one step and, in the case of enone 7, gave the tetracycle 13 as a single diastereoisomer in up to 67% yield.
mechanistic insights, carbonyl-compounds, iodide, reduction, hydrodimerization, cyclizations, halides
1523-7060
1943-1945
Howells, Dean M.
e91b7f3d-ed6b-4f43-8ab4-c98dc86ef9c7
Barker, Sarah M.
d4c8400a-eeff-45d8-8ce8-cb28746d2d25
Watson, Faye C.
e00d8ed6-beb8-47a7-ae99-90519ecdf7a4
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Kilburn, Jeremy D.
e64ded70-825a-40ec-816b-c4605e007e7a
Howells, Dean M.
e91b7f3d-ed6b-4f43-8ab4-c98dc86ef9c7
Barker, Sarah M.
d4c8400a-eeff-45d8-8ce8-cb28746d2d25
Watson, Faye C.
e00d8ed6-beb8-47a7-ae99-90519ecdf7a4
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Kilburn, Jeremy D.
e64ded70-825a-40ec-816b-c4605e007e7a

Howells, Dean M., Barker, Sarah M., Watson, Faye C., Light, Mark E., Hursthouse, Michael B. and Kilburn, Jeremy D. (2004) Samarium diiodide coupling of enones: a remarkable cascade sequence. Organic Letters, 6 (12), 1943-1945. (doi:10.1021/ol049563w).

Record type: Article

Abstract

Treatment of cyclic enones with SmI2 in THF/MeOH (4:1) led to tricyclic diol products in one step and, in the case of enone 7, gave the tetracycle 13 as a single diastereoisomer in up to 67% yield.

This record has no associated files available for download.

More information

Published date: 10 June 2004
Related URLs:
Keywords: mechanistic insights, carbonyl-compounds, iodide, reduction, hydrodimerization, cyclizations, halides
Learn more about Chemistry research

Identifiers

Local EPrints ID: 20238
URI: http://eprints.soton.ac.uk/id/eprint/20238
DOI: doi:10.1021/ol049563w
ISSN: 1523-7060
PURE UUID: 3a3a9512-d82a-4f4c-a8d8-7e9424bc8a7e
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 03:04

Export record

Altmetrics

Contributors

Author: Dean M. Howells
Author: Sarah M. Barker
Author: Faye C. Watson
Author: Mark E. Light ORCID iD
Author: Michael B. Hursthouse
Author: Jeremy D. Kilburn

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×