Synthesis of phosphinines and phosphinanes using zirconium chemistry
Synthesis of phosphinines and phosphinanes using zirconium chemistry
Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.
phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid
immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles
7633-7636
Hunter, R. A.
589bb215-7967-44fa-aad0-539ff7451734
Whitby, R. J.
45632236-ab00-4ad0-a02d-6209043e818b
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
4 October 2004
Hunter, R. A.
589bb215-7967-44fa-aad0-539ff7451734
Whitby, R. J.
45632236-ab00-4ad0-a02d-6209043e818b
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Hunter, R. A., Whitby, R. J., Light, M. E. and Hursthouse, M. B.
(2004)
Synthesis of phosphinines and phosphinanes using zirconium chemistry.
Tetrahedron Letters, 45 (41), .
(doi:10.1016/j.tetlet.2004.08.098).
Abstract
Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.
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Published date: 4 October 2004
Keywords:
phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid
immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles
Identifiers
Local EPrints ID: 20241
URI: http://eprints.soton.ac.uk/id/eprint/20241
ISSN: 0040-4039
PURE UUID: 58c7a981-d5a0-416a-b951-29658001f2aa
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Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 03:04
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Author:
R. A. Hunter
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