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Synthesis of phosphinines and phosphinanes using zirconium chemistry

Record type: Article

Ring expansion of readily available zirconacyclopentadienes or zirconacyclopentanes by insertion of chloro(trimethylsilyl)rnethyllithium followed by metathesis with phosphorous trichloride provides a novel route to lambda(3)-phosphinines (phosphabenzenes) or phosphinanes.

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Citation

Hunter, R. A., Whitby, R. J., Light, M. E. and Hursthouse, M. B. (2004) Synthesis of phosphinines and phosphinanes using zirconium chemistry Tetrahedron Letters, 45, (41), pp. 7633-7636. (doi:10.1016/j.tetlet.2004.08.098).

More information

Published date: 4 October 2004
Keywords: phosphinine, phosphinane, phosphinic acid, zirconacycle, carbenoid immunodeficiency virus-1 protease, metallacycle transfer, carbenoidinsertion, complexes, zirconacyclopentadienes, zirconacycles, derivatives, ligands, phosphabenzenes, heterocycles

Identifiers

Local EPrints ID: 20241
URI: http://eprints.soton.ac.uk/id/eprint/20241
ISSN: 0040-4039
PURE UUID: 58c7a981-d5a0-416a-b951-29658001f2aa
ORCID for R. J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502
ORCID for M. E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 20 Feb 2006
Last modified: 17 Jul 2017 16:29

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Contributors

Author: R. A. Hunter
Author: R. J. Whitby ORCID iD
Author: M. E. Light ORCID iD

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