Exceptional electron donating ability of an extended tetrathiafulvalene derivative
Exceptional electron donating ability of an extended tetrathiafulvalene derivative
We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.
tetrathiafulvalene, synthesis, x-ray crystallography, electrochemistry, chemistry, salts
2535-2539
Khan, Tahir
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Skabara, Peter J.
7138e414-7d50-41c7-933e-0bccad2fa4cd
Frère, Pierre
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Allain, Magali
1e2cf6c8-786c-4930-9c74-1f54cb0fc195
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
15 March 2004
Khan, Tahir
62b62b1c-8266-451d-bcbe-9c4aa09c3440
Skabara, Peter J.
7138e414-7d50-41c7-933e-0bccad2fa4cd
Frère, Pierre
6bf843b8-082d-4682-987c-2691df02230c
Allain, Magali
1e2cf6c8-786c-4930-9c74-1f54cb0fc195
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Khan, Tahir, Skabara, Peter J., Frère, Pierre, Allain, Magali, Coles, Simon J. and Hursthouse, Michael B.
(2004)
Exceptional electron donating ability of an extended tetrathiafulvalene derivative.
Tetrahedron Letters, 45 (12), .
(doi:10.1016/j.tetlet.2004.02.003).
Abstract
We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.
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Published date: 15 March 2004
Additional Information:
Short communication
Keywords:
tetrathiafulvalene, synthesis, x-ray crystallography, electrochemistry, chemistry, salts
Identifiers
Local EPrints ID: 20254
URI: http://eprints.soton.ac.uk/id/eprint/20254
ISSN: 0040-4039
PURE UUID: e3816003-d988-4038-b4b2-b48e86e473ec
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Date deposited: 17 Feb 2006
Last modified: 16 Mar 2024 03:05
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Contributors
Author:
Tahir Khan
Author:
Peter J. Skabara
Author:
Pierre Frère
Author:
Magali Allain
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