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A mixed-halogen tricarbonyl manganese(I) complex: fac- MnBr0.3Cl0.7{Ph2P(CH2)(3)PPh2}(CO)(3)

A mixed-halogen tricarbonyl manganese(I) complex: fac- MnBr0.3Cl0.7{Ph2P(CH2)(3)PPh2}(CO)(3)
A mixed-halogen tricarbonyl manganese(I) complex: fac- MnBr0.3Cl0.7{Ph2P(CH2)(3)PPh2}(CO)(3)
Crystals of the mixed halogen complex, fac-(bromo/chloro)tricarbonyl[ 1,3-bis(diphenylphosphino) propane] manganese( I), fac-[MnBr0.3Cl0.7(C30H26O3P2)(CO)(3)], were obtained from a prolonged recrystallization attempt of [MnBr{Ph2P(CH2)(3)PPh2}( CO)(3)] from CHCl3/hexane solution at 263 K. Common coordinates are found for all but the halogen atoms in the disordered structure, but the Mn-X vectors differ by 3.5 (5)degrees and the M - X bond lengths differ by 0.10 ( 1) Angstrom.
2056-9890
M1245-M1247
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, M.A.
59bc94ea-6a41-48ac-9467-7638986fe34a
Brassington, D.S.
22fc77cd-c713-4bf4-9b2c-969136d93429
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, M.A.
59bc94ea-6a41-48ac-9467-7638986fe34a
Brassington, D.S.
22fc77cd-c713-4bf4-9b2c-969136d93429

Light, M.E., Hursthouse, M.B., Beckett, M.A. and Brassington, D.S. (2004) A mixed-halogen tricarbonyl manganese(I) complex: fac- MnBr0.3Cl0.7{Ph2P(CH2)(3)PPh2}(CO)(3). Acta Crystallographica Section E: Crystallographic Communications, 60 (9), M1245-M1247. (doi:10.1107/S1600536804019385).

Record type: Article

Abstract

Crystals of the mixed halogen complex, fac-(bromo/chloro)tricarbonyl[ 1,3-bis(diphenylphosphino) propane] manganese( I), fac-[MnBr0.3Cl0.7(C30H26O3P2)(CO)(3)], were obtained from a prolonged recrystallization attempt of [MnBr{Ph2P(CH2)(3)PPh2}( CO)(3)] from CHCl3/hexane solution at 263 K. Common coordinates are found for all but the halogen atoms in the disordered structure, but the Mn-X vectors differ by 3.5 (5)degrees and the M - X bond lengths differ by 0.10 ( 1) Angstrom.

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Published date: 1 September 2004
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Identifiers

Local EPrints ID: 20275
URI: http://eprints.soton.ac.uk/id/eprint/20275
DOI: doi:10.1107/S1600536804019385
ISSN: 2056-9890
PURE UUID: 1c6743a9-c740-49ea-bc0b-36485f3c6a15
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 03:04

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Author: M.E. Light ORCID iD
Author: M.B. Hursthouse
Author: M.A. Beckett
Author: D.S. Brassington

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