A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands
A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands
Sharpless asymmetric dihydroxylation ligands were synthesized using a triazine spacer group in two, high yielding steps from cheap, readily available starting materials. The ligands, gave good enantioselectivities in the asymmetric dihydroxylation of alkenes and may provide a very economic alternative to current systems.
triazine, sharpless, dihydroxylation, high enantioselectivity, olefins, ad, mechanism, alkenes
8527-8529
McNamara, Catherine Anne
9d78c411-de46-4f2d-aece-b85732a392c6
King, Frank
657c50d7-5cbd-408a-a581-f9e286ed4d3a
Bradley, M.ark
1ce668c3-ebe0-4add-a5f0-abfc25cb0415
8 November 2004
McNamara, Catherine Anne
9d78c411-de46-4f2d-aece-b85732a392c6
King, Frank
657c50d7-5cbd-408a-a581-f9e286ed4d3a
Bradley, M.ark
1ce668c3-ebe0-4add-a5f0-abfc25cb0415
McNamara, Catherine Anne, King, Frank and Bradley, M.ark
(2004)
A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands.
Tetrahedron Letters, 45 (46), .
(doi:10.1016/j.tetlet.2004.09.098).
Abstract
Sharpless asymmetric dihydroxylation ligands were synthesized using a triazine spacer group in two, high yielding steps from cheap, readily available starting materials. The ligands, gave good enantioselectivities in the asymmetric dihydroxylation of alkenes and may provide a very economic alternative to current systems.
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Published date: 8 November 2004
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Short communication
Keywords:
triazine, sharpless, dihydroxylation, high enantioselectivity, olefins, ad, mechanism, alkenes
Identifiers
Local EPrints ID: 20286
URI: http://eprints.soton.ac.uk/id/eprint/20286
ISSN: 0040-4039
PURE UUID: 254c9c87-cc56-4811-b9c9-013439dfef9a
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Date deposited: 17 Feb 2006
Last modified: 15 Mar 2024 06:23
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Contributors
Author:
Catherine Anne McNamara
Author:
Frank King
Author:
M.ark Bradley
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