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A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands

A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands
A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands
Sharpless asymmetric dihydroxylation ligands were synthesized using a triazine spacer group in two, high yielding steps from cheap, readily available starting materials. The ligands, gave good enantioselectivities in the asymmetric dihydroxylation of alkenes and may provide a very economic alternative to current systems.
triazine, sharpless, dihydroxylation, high enantioselectivity, olefins, ad, mechanism, alkenes
0040-4039
8527-8529
McNamara, Catherine Anne
9d78c411-de46-4f2d-aece-b85732a392c6
King, Frank
657c50d7-5cbd-408a-a581-f9e286ed4d3a
Bradley, M.ark
1ce668c3-ebe0-4add-a5f0-abfc25cb0415
McNamara, Catherine Anne
9d78c411-de46-4f2d-aece-b85732a392c6
King, Frank
657c50d7-5cbd-408a-a581-f9e286ed4d3a
Bradley, M.ark
1ce668c3-ebe0-4add-a5f0-abfc25cb0415

McNamara, Catherine Anne, King, Frank and Bradley, M.ark (2004) A triazine core for a new class of Sharpless asymmetric dihydroxylation ligands. Tetrahedron Letters, 45 (46), 8527-8529. (doi:10.1016/j.tetlet.2004.09.098).

Record type: Article

Abstract

Sharpless asymmetric dihydroxylation ligands were synthesized using a triazine spacer group in two, high yielding steps from cheap, readily available starting materials. The ligands, gave good enantioselectivities in the asymmetric dihydroxylation of alkenes and may provide a very economic alternative to current systems.

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More information

Published date: 8 November 2004
Additional Information: Short communication
Keywords: triazine, sharpless, dihydroxylation, high enantioselectivity, olefins, ad, mechanism, alkenes

Identifiers

Local EPrints ID: 20286
URI: http://eprints.soton.ac.uk/id/eprint/20286
ISSN: 0040-4039
PURE UUID: 254c9c87-cc56-4811-b9c9-013439dfef9a

Catalogue record

Date deposited: 17 Feb 2006
Last modified: 15 Mar 2024 06:23

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Contributors

Author: Catherine Anne McNamara
Author: Frank King
Author: M.ark Bradley

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