Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO
Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO
Synchronous, time resolved, infra-red, XAFS, and mass spectroscopies are simultaneously applied in situ to the investigation of the dynamic behaviour of Rh/Al2O3 catalysts during NO reduction by CO; NO conversion, and its kinetic character are closely correlated to the conversion of Rh(I) (predominantly Rh-I(CO)(2)) to Rh(0).
absorption fine-structure, rh/al2o3, rhodium, spectroscopy, alumina
2382-2383
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Jyoti, Bhrat
9e00e347-0864-48fa-9bb8-f44f98161fd0
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
7 November 2004
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Jyoti, Bhrat
9e00e347-0864-48fa-9bb8-f44f98161fd0
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Newton, Mark A., Jyoti, Bhrat, Dent, Andrew J., Fiddy, Steven G. and Evans, John
(2004)
Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO.
Chemical Communications, 2004 (21), .
(doi:10.1039/b405694a).
Abstract
Synchronous, time resolved, infra-red, XAFS, and mass spectroscopies are simultaneously applied in situ to the investigation of the dynamic behaviour of Rh/Al2O3 catalysts during NO reduction by CO; NO conversion, and its kinetic character are closely correlated to the conversion of Rh(I) (predominantly Rh-I(CO)(2)) to Rh(0).
This record has no associated files available for download.
More information
Published date: 7 November 2004
Additional Information:
This research resulted in the instrumentation being replicated at the beamline ID24 at the ESRF (Grenoble) to become available to other researchers across Europe. This we tested in July 2006.
Keywords:
absorption fine-structure, rh/al2o3, rhodium, spectroscopy, alumina
Identifiers
Local EPrints ID: 20293
URI: http://eprints.soton.ac.uk/id/eprint/20293
ISSN: 1359-7345
PURE UUID: 1910e2e1-c50e-4fea-90e9-13afe712346e
Catalogue record
Date deposited: 20 Feb 2006
Last modified: 29 Oct 2024 02:32
Export record
Altmetrics
Contributors
Author:
Mark A. Newton
Author:
Bhrat Jyoti
Author:
Andrew J. Dent
Author:
Steven G. Fiddy
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
